• 专利标题:   Graphene reinforced and toughened biodegradable polyester compound used for composite foam material, is prepared by dispersing graphene oxide, dissolving epoxy chain extender, performing acetone washing, and blending polylactic acid.
  • 专利号:   CN111320845-A
  • 发明人:   DI W, ZHAO D
  • 专利权人:   UNIV SUN YATSEN
  • 国际专利分类:   C08J005/18, C08J009/12, C08K003/04, C08K009/04, C08L067/02, C08L067/04
  • 专利详细信息:   CN111320845-A 23 Jun 2020 C08L-067/02 202059 Pages: 6 Chinese
  • 申请详细信息:   CN111320845-A CN10224169 26 Mar 2020
  • 优先权号:   CN10224169

▎ 摘  要

NOVELTY - Graphene reinforced and toughened biodegradable polyester compound, is prepared by (a) dispersing graphene oxide (GO) in water through a high-energy ultrasonic probe, freeze-drying the GO aqueous solution to obtain fluffy GO powder, and dispersing fluffy GO powder in dimethylformamide (DMF) using high-energy ultrasound to prepare GO/DMF dispersion, (b) dissolving multifunctional epoxy chain extender in DMF by vigorous stirring, adding the obtained dispersion to the GO/DMF dispersion, continuously stirring, adding triphenylphosphine catalyst to the dispersion to induce chemical reaction, through multiple filtration, performing acetone washing and drying, so as to obtain GO-epoxy powder, and (c) melting and blending dried polybutylene adipate terephthalate (PBAT), polylactic acid (PLA) and GO-epoxy powder and molding by a circulating twin-screw internal mixer to obtain target composite sheet. USE - The biodegradable polyester compound is useful as a composite sheet for a composite foam material (claimed). ADVANTAGE - The biodegradable polyester compound improves the compatibility of the PBAT/PLA composite, and has a tensile strength of 25-55 MPa and an elongation at break of 100-600%, low density, high hardness, high strength, and high toughness. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a graphene reinforced and toughened biodegradable polyester composite foam material, prepared by saturating the above-mentioned composite sheet with high-pressure fluid, and performing rapid pressure relief foaming to obtain the product.