• 专利标题:   Preparing graphene-modified nylon composite material, by dispersing graphene in mixed acid solution, reacting, washing, filtering, drying, heat-treating, dissolving heat-treated graphene oxide and nylon 46 in formic acid, washing and drying.
  • 专利号:   CN111087807-A
  • 发明人:   LU F, GAN D, SONG K, HU T
  • 专利权人:   ZHUZHOU TIMES ENG PLASTICS TECHNOLOGY CO
  • 国际专利分类:   C08K003/04, C08K009/00, C08L077/06
  • 专利详细信息:   CN111087807-A 01 May 2020 C08L-077/06 202042 Pages: 6 Chinese
  • 申请详细信息:   CN111087807-A CN11382379 27 Dec 2019
  • 优先权号:   CN11382379

▎ 摘  要

NOVELTY - Method for preparing graphene-modified nylon composite material, involves (i) dispersing graphene in mixed acid solution of concentrated sulfuric acid and concentrated nitric acid, ultrasonically processing for 12-24 hours, stirring and reacting at 50-80 degrees C for 6-8 hours, washing, filtering and drying to obtain graphene oxide, (ii) heat-treating graphene oxide obtained in step (i) at 400-800 degrees C under protection of inert gas for 1-2 hours to obtain heat-treated graphene oxide, (iii) dissolving heat-treated graphene oxide obtained in step (ii) and nylon 46 in formic acid, stirring, and ultrasonically processing to obtain mixed solution, where the amount of heat-treated graphene oxide is 0.1-2 %mass, (iv) placing mixed solution obtained in step (iii) in a reaction kettle at 1.5-2 MPa and 150-160 degrees C for 3-5 hours, releasing pressure and cooling to obtain mixed suspension, and (v) adding deionized water to mixed suspension obtained in step (iv), washing and drying. USE - The method is useful for preparing graphene-modified nylon composite material (claimed). ADVANTAGE - The method improves the compatibility problem between graphene and nylon, and improves tensile strength, bending strength and friction coefficient of the graphene-modified nylon composite material.