• 专利标题:   Preparation of electrode involves carrying out constant-voltage electrochemical reaction using graphene oxide-deposited foamed nickel as working electrode, and immersing obtained electrode in aqueous solution of carbon nanotubes.
  • 专利号:   CN103258656-A, CN103258656-B
  • 发明人:   XIAO F, WANG S, ZHANG Z
  • 专利权人:   UNIV HUAZHONG SCI TECHNOLOGY
  • 国际专利分类:   H01G011/30, H01G011/56, H01G011/86
  • 专利详细信息:   CN103258656-A 21 Aug 2013 H01G-011/86 201406 Pages: 17 Chinese
  • 申请详细信息:   CN103258656-A CN10146410 25 Apr 2013
  • 优先权号:   CN10146410

▎ 摘  要

NOVELTY - Preparation of electrode involves washing foamed nickel and soaking the foamed nickel into a graphene oxide aqueous solution to obtain graphene oxide-deposited foamed nickel, and forming positive electrode by carrying out constant-voltage electrochemical reaction using graphene oxide-deposited foamed nickel as a working electrode, a molybdenum electrode as auxiliary electrode and a saturated calomel electrode as a reference electrode and 0.1-1 mol/L sulfate as electrolyte solution and immersing the obtained electrode in an aqueous solution of carbon nanotubes and drying. USE - Preparation of electrode used for dissymmetric supercapacitor (claimed). ADVANTAGE - The method enables economical preparation of electrode under reduced energy consumption. The supercapacitor containing the electrode has improved energy density and high specific capacitance. DETAILED DESCRIPTION - Preparation of electrode involves washing foamed nickel and soaking the foamed nickel into a graphene oxide aqueous solution to obtain graphene oxide-deposited foamed nickel, and forming positive electrode by carrying out constant-voltage electrochemical reaction using graphene oxide-deposited foamed nickel as a working electrode, a molybdenum electrode as auxiliary electrode and a saturated calomel electrode as a reference electrode and 0.1-1 mol/L sulfate as electrolyte solution and immersing the obtained electrode in an aqueous solution of carbon nanotubes with concentration of 0.2-2 mg/ml and drying, or forming negative electrode by carrying out constant-voltage electrochemical reaction using graphene oxide-deposited foamed nickel as a working electrode, a molybdenum electrode as auxiliary electrode, a saturated calomel electrode as a reference electrode and 0.1-1 mol/L aqueous solution of manganese acetate as electrolyte solution and immersing the obtained electrode in an aqueous solution of manganese oxide. An INDEPENDENT CLAIM is included for dissymmetric supercapacitor.