• 专利标题:   Method for preparing laminated cobalt zinc hydroxide-graphene composite super capacitor electrode, involves dispersing oxidized graphene and surfactant by ultrasonically in aqueous urea solution, followed by washing composites and drying.
  • 专利号:   CN106206055-A
  • 发明人:   GAO Z, ZHANG L, CHANG J, WU D, XU F, JIANG K
  • 专利权人:   UNIV HENAN NORMAL
  • 国际专利分类:   H01G011/30, H01G011/86
  • 专利详细信息:   CN106206055-A 07 Dec 2016 H01G-011/30 201709 Pages: 7 Chinese
  • 申请详细信息:   CN106206055-A CN10598940 27 Jul 2016
  • 优先权号:   CN10598940

▎ 摘  要

NOVELTY - A laminated cobalt zinc hydroxide-graphene composite super capacitor electrode preparing method involves, dispersing oxidized graphene and surfactant by ultrasonically in aqueous urea solution. The cobalt nitrate hexahydrate and zinc acetate dihydrate is added into the graphene oxide suspension. The precursor solution is transferred to a hydrothermal reaction kettle. The hydrotalcite-like layered cobalt-zinc double hydroxides-graphene composites are deposited on the surface of nickel foam collector, and washed by ultrasonic and dried. USE - Method for preparing laminated cobalt zinc hydroxide-graphene composite super capacitor electrode. ADVANTAGE - The method enables preparing the laminated cobalt zinc hydroxide-graphene composite super capacitor electrode with high specific capacity and better effect of multiplying power performance, in a cost effective manner. DETAILED DESCRIPTION - A laminated cobalt zinc hydroxide-graphene composite super capacitor electrode preparing method involves, dispersing 4-100 mg oxidized graphene and 4-200 mg surfactant by ultrasonically in 40 mL aqueous urea solution having a molar concentration of 2 mol/L to form an oxidized graphene suspension. The cobalt nitrate hexahydrate and zinc acetate dihydrate having a molar ratio of 1:3-3:1 is added into the graphene oxide suspension to form homogeneous precursor solution. The precursor solution is transferred to a hydrothermal reaction kettle while immersing foamed nickel current collector into the precursor solution in the hydrothermal reaction kettle at 120-180 degrees C for 5-10 hours. The hydrotalcite-like layered cobalt-zinc double hydroxides-graphene composites are deposited on the surface of nickel foam collector, and washed by ultrasonic and dried to obtain finished product, where the cobalt nitrate hexahydrate and zinc acetate having a total molar amount of 4x 10-3 mol.