▎ 摘 要
NOVELTY - Manufacturing high-flammable thermoplastic elastomer composition comprises e.g. maintaining feeder temperature of twin extruder at 40-60° C and raising the internal temperature of the extruder equipped with the screw to 80-160° C, adding 10000 pts. wt. ethylene copolymer or polyethylene resin into the feeder and melting, adding then calcium stearate or zinc stearate, adding 100-500 pts. wt. lubricant including barium stearate and 4,000-8,000 pts. wt. red phosphorus, kneading for 10-60 minutes, making polymer pellet having a size of about 2-5 mm by cutting through a melt extrusion molding process, continuously supplying calcium hydroxide, 10,000 pts. wt. flame retardant comprising metal hydrate in aluminum hydroxide or magnesium hydroxide and ethanol, isopropyl alcohol, chloroform, organic solvent comprising dimethylsulfoxide, pentadecanoic acid, hexadecanoic acid, octadecanoic acid, fatty acids comprising dodecanoic acid through-flow blender, kneading and filtering. USE - The high-flammable thermoplastic elastomer composition is useful for polar navigation ship cable . ADVANTAGE - The high-flammable thermoplastic elastomer composition has flexibility, cold resistance, oil resistance, and icing resistance. DETAILED DESCRIPTION - Manufacturing high-flammable thermoplastic elastomer composition comprises maintaining feeder temperature of twin extruder at 40-60° C and raising the internal temperature of the extruder equipped with the screw to 80-160° C, adding 10000 pts. wt. ethylene copolymer or polyethylene resin into the feeder and melting, adding then calcium stearate or zinc stearate, adding 100-500 pts. wt. lubricant including barium stearate and 4,000-8,000 pts. wt. red phosphorus, kneading for 10-60 minutes, making polymer pellet having a size of about 2-5 mm by cutting through a melt extrusion molding process, where magnesium hydroxide phosphate has an average particle diameter of 0.1-20 μ m, continuously supplying calcium hydroxide, 10,000 pts. wt. flame retardant comprising metal hydrate in aluminum hydroxide or magnesium hydroxide and ethanol, isopropyl alcohol, chloroform, 7,500-15,000 pts. wt. organic solvent comprising dimethylsulfoxide, pentadecanoic acid, hexadecanoic acid, octadecanoic acid, 2,500-5,000 pts. wt. fatty acids comprising dodecanoic acid through-flow blender and kneading and filtering at 60-120° C, preparing a flame retardant surface-treated with fatty acid by drying, adding 9500 pts. wt. alcohol e.g. methanol or ethanol, 500 pts. wt. distilled water, vinyl silane, tris(methoxyethoxy)vinyl silane, or trisisopropyl-vinylsilane, trimethoxy(vinyl)silane, tetraethoxy silane, methyltriethoxysilane, methyltrimethoxysilane, methyltri(2-methoxyethoxy)silane, 3-methacryloyloxypropyl-trimethoxysilane, 3-mercaptopropyl-trimethoxysilane (3-mercaptopropyl-trimethoxysilane), 1,000-5,000 reactive silanes that are individually or more than two including 3-aminopropyl-trimethoxysilane 500-2,000 pts. wt. acid catalyst e.g. hydrochloric acid or acetic acid, 19,000-45,000 pts. wt. flame retardant having an average particle diameter of 0.01-20 μ m in a solution stirred for 20-60 minutes at a speed of 50-300 rotations/minute while maintaining pH 3-5 in a reactor equipped with a stirrer, preparing flame retardant surface-treated with silane by adding it, stirring at a speed of 50-300 rotations/minute for 20-120 minutes, filtering, and drying at 60-120° C, polyethylene or ethylene-propylene copolymer, 10,000 pts. wt. ethylene polymer or an ethylene copolymer comprising ethylene-propylene-diene copolymer, 6,000-10,000 pts. wt. surface-treated flame retardant prepared in fatty acid surface treatment step of flame retardant or silane surface treatment step of the flame retardant, 10-1,200 pts. wt. reinforcing agent comprising silica or carbon black, magnesium carbonate, aluminum silicate, magnesium silicate, and diatomaceous earth, 1-600 pts. wt. zinc oxide, thiodiethylene bis3-(3,5-di-tert-butyl-4-hydrooxyphenyl)propionate, or thiodipropionic acid dioctadecylester), distearyl thiodipropionate, and/or sulfur compounds in 3-mercaptopropionic acid and 5-20 pts. wt. antioxidant, 10-120 pts. wt. fatty acid or fatty acid metal salt lubricant, sequentially transferring dough kneaded at 80-130° C for 5-60 minutes to a single screw or twin screw extruder to produce pellets of insulation composition with a size of 3-5 mm through extrusion molding, then separate kneader or Hensel, preparing cross-linked insulating composition pellets by administering 100-500 pts. wt. organic peroxide to 16,025-21,340 pts. wt. insulating composition pellets in a mixing mixer in Banbury and kneading for 10-60 minutes at a temperature of 60-100° C, mixing 10,000 pts. wt. polymer elastomer and electro-conductive carbon black in a mixer, kneading in Henschel, or Banbury, adding carbon nanotube, graphite, 500-2,000 pts. wt. electrically conductive filler comprising graphene, 43-64 pts. wt. antioxidant and 25-40 pts. wt. fatty acid or fatty acid metal salt lubricant, sequentially adding and kneading at 100-140° C for 10-60 minutes, transferring dough to a single screw or twin screw extruder, preparing semiconducting elastomer pellets of the size 3-5 mm with a surface resistance of 105-108 Ω through extrusion molding. An INDEPENDENT CLAIM is also included for polar navigation ship cable coated with high-flammable thermoplastic elastomer, comprising a cross-linkable semi-conductive elastic layer and cross-linked insulating layer on a conductor made of a metal wire, a metal plated wire, or a metal alloy wire. An insulated wire in which a cross-linked semi-conductive elastic layer is sequentially formed, a shielding layer by tapping the outer periphery of the insulated wire with a metal tape or a metal coating film or braiding with a metal wire in a metal wire, a metal plated wire, or an alloy wire. A tape layer on outer periphery of the shielding layer by taping with any one binder tape of polyester, polyketone, polyimide, and polysulfone tape is formed. An inner coating layer made of a thermoplastic elastomer composition on the outer periphery of the insulated wire on which the tape layer is formed. In the outer periphery of the inner coating layer, metal wires e.g. copper wire, metal plated copper wire, iron wire, nickel wire, or glass fiber yarn, basalt fiber yarn, elvan fiber yarn, ceramic fiber yarn, inorganic fiber yarn such as carbon fiber yarn, aramid fiber yarns are braided and braided to form a reinforcing layer. An outer coating layer with a thermoplastic elastomer composition on the outer periphery of the reinforcing layer is formed.