• 专利标题:   Antistatic polyamide composite material comprises aliphatic dibasic acid, aliphatic diamine, nano graphene aqueous solution, blocking agent, catalyst and deionized water, and has better thermal properties, and mechanical properties.
  • 专利号:   CN108219131-A
  • 发明人:   YANG G, ZHAO D, YAN L
  • 专利权人:   SHANGHAI GENIUS ADVANCED MATERIAL CO LTD
  • 国际专利分类:   C08G069/28, C08G069/26, C08K003/04
  • 专利详细信息:   CN108219131-A 29 Jun 2018 C08G-069/28 201855 Pages: 11 Chinese
  • 申请详细信息:   CN108219131-A CN11199789 22 Dec 2016
  • 优先权号:   CN11199789

▎ 摘  要

NOVELTY - Antistatic polyamide composite material comprises 20-80 pts. wt. aliphatic dibasic acid, 20-80 pts. wt. aliphatic diamine, 5-100 pts. wt. nano graphene aqueous solution, 0.1-0.4 pts. wt. blocking agent, 0.01-0.06 pts. wt. catalyst and 30-160 pts. wt. deionized water. USE - Antistatic polyamide composite material. ADVANTAGE - The antistatic polyamide composite material has better thermal properties, mechanical properties and good antistatic property, greatly broadens the range of processing and use temperature of the manufactured products, satisfies the requirements for use of various environmental temperatures and people flexibly adjusts the nano-scale graphene content in the products according to the anti-static requirements in practical applications to meet the requirements of practical applications. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing an antistatic polyamide composite material, which involves: (A) adding 20-80 pts. wt. aliphatic dibasic acid, 20-80 pts. wt. aliphatic diamine, 5-100 pts. wt. nano graphene aqueous solution, 0.1-0.4 pts. wt. blocking agent, 0.01-0.06 pts. wt. catalyst and 30-160 pts. wt. deionized water to the autoclave; (B) vacuuming high pressure reaction kettle to nitrogen, and then the pressure is adjusted to be higher than the normal pressure of 30-50 kPa; (C) heating the high pressure reaction kettle, heating to the first temperature, the pressure is increased to 0.1-0.2 MPa, and then the constant temperature reaction is carried out for 1-3 hours; (D) raising the temperature to the second temperature and increasing the pressure to 1-3 MPa while maintaining the pressure constant; (E) heating up at a rate of 0.2-1.8 degrees C/min for 1-3 hours to a third temperature, the pressure is 1-3 MPa; (F) raising temperature, the pressure in the autoclave is released to normal pressure, and the pressure relief time is 0.5-2 hours, while maintaining the temperature constant until no exhaust gas escapes; and (G) completing reaction, the autoclave is filled with nitrogen gas, the pressure is adjusted to 0.5-1.0 MPa, and finally the material is pressed out of the strand to pelletize to obtain the antistatic polyamide composite material.