• 专利标题:   High-strength room-temperature self-repairing polyurea coating material molecular structure comprises hemithioacetal group and urea group.
  • 专利号:   CN113969096-A, CN113969096-B
  • 发明人:   XIA H, WANG Z
  • 专利权人:   UNIV SICHUAN
  • 国际专利分类:   C08G018/50, C08G018/61, C08G018/84, C08G075/10, C09D175/02, C09D005/08, H01B001/24
  • 专利详细信息:   CN113969096-A 25 Jan 2022 C09D-175/02 202248 Chinese
  • 申请详细信息:   CN113969096-A CN11434634 29 Nov 2021
  • 优先权号:   CN11434634

▎ 摘  要

NOVELTY - High-strength room-temperature self-repairing polyurea coating material molecular structure comprises hemithioacetal group and urea group. The high-strength room temperature self-repairing polyurea coating material molecular structure is compound (I). USE - Used as high-strength room-temperature self-repairing polyurea coating material. ADVANTAGE - The polyurea coating material molecular structure: utilizes dynamic reversible hemithioacetal groups and urea bond groups to achieve rapid room temperature self-repairing of polyurea materials; and utilizes phase separation to improve the mechanical properties of room-temperature self-repairing polyurea materials. DETAILED DESCRIPTION - High-strength room-temperature self-repairing polyurea coating material molecular structure comprises hemithioacetal group and urea group. The high-strength room temperature self-repairing polyurea coating material molecular structure is compound of formula (I). n, m, R, R1 and R2 = not defined; An INDEPENDENT CLAIM is also included for preparing high-strength room temperature self-repairing polyurea coating material molecular structure comprising (i) stirring the mercapto compound with a functionality of greater than or equal to2 and aldehyde compound with a functionality of greater than or equal to2 in a solvent in a certain proportion until the viscosity no longer increases to obtain aldehyde group-terminated polyhemithioacetal precursor, (ii) stirring the amino compound with functionality of greater than or equal to2 and an isocyanate compound with a functionality of greater than or equal to2 in a solvent in a certain proportion until the viscosity no longer increases to obtain amino-terminated polyurea precursor, (iii) mixing the precursor solutions obtained in step (i) and step (ii), stirring and reacting for 1 hour, pouring into a mold, and volatilizing the solvent to obtain polyurea material with self-repairing function at room temperature, (iv) dispersing graphene oxide in a solvent, mixing with the precursor solutions obtained in steps (i) and (ii), stirring and reacting for 1 hour, and spraying on the surface of the substrate with a spray gun to obtain graphene oxide/polyurea composite anti-corrosion coating material with self-healing function at room temperature, and (v) dispersing graphene in a solvent, mixing it with the precursor solutions obtained in steps (i) and (ii), stirring and reacting for 1 hour, pouring it into a mold, and volatilizing the solvent to obtain graphene/polyurea composite conductive material with self-healing function at room temperature.