• 专利标题:   Preparing graphene oxide and titanium oxide nanoparticle composite material comprises e.g. dissolving graphite oxide in water, ultrasonic processing, mixing titanium dioxide with graphite oxide solution, and performing hydrothermal reaction.
  • 专利号:   CN103143337-A, CN103143337-B
  • 发明人:   TIAN H, ZHENG W, JIN C
  • 专利权人:   UNIV JILIN
  • 国际专利分类:   B01J021/18
  • 专利详细信息:   CN103143337-A 12 Jun 2013 B01J-021/18 201378 Pages: 10 Chinese
  • 申请详细信息:   CN103143337-A CN10080088 14 Mar 2013
  • 优先权号:   CN10080088

▎ 摘  要

NOVELTY - Preparing graphene oxide and titanium oxide nanoparticle composite material comprises (i) dissolving graphite oxide in deionized water, ultrasonic processing and separating the graphite oxide layer to obtain graphene oxide; (ii) mixing titanium dioxide with ultrasonic treated graphite oxide solution, magnetic stirring for 1 hour; (iii) pouring the obtained suspension into a reaction kettle, sealing and carrying out hydrothermal reaction at 120-180 degrees C for 4-8 hours; and (iv) washing the suspension with deionized water, centrifuging and drying. USE - The method is useful for preparing graphene oxide and titanium oxide nanoparticle composite material (claimed). ADVANTAGE - The method: is simple, economical and suitable for mass production, ensures easy operation, has high stability and repeatability; does not utilize additives and is environmentally friendly; and improves deposition or adhesion performance of titanium dioxide nanoparticles on a graphene oxide substrate. The composite material has good catalytic performance and degrades the dye even in a dark condition. DETAILED DESCRIPTION - Preparing graphene oxide and titanium oxide nanoparticle composite material comprises (i) dissolving graphite oxide in deionized water, where the concentration of graphite oxide solution is 0.66-2.67 g/l, ultrasonic processing for 30-60 minutes, where the ultrasonic power is 40-100 W and separating the graphite oxide layer to obtain graphene oxide; (ii) mixing titanium dioxide with ultrasonic treated graphite oxide solution, magnetic stirring for 1 hour, where the mass ratio of graphite oxide and titanium dioxide is 1-4:5; (iii) pouring the obtained suspension into a reaction kettle, sealing and carrying out hydrothermal reaction at 120-180 degrees C for 4-8 hours; and (iv) washing the suspension with deionized water, centrifuging and drying.