• 专利标题:   Producing a cathode active material including graphene-silicon complex useful in lithium secondary battery as power sources for mobile electronic devices comprises combining silicon-containing particles on reduced graphene oxide sheets.
  • 专利号:   KR2244194-B1, WO2022086098-A1, CN115349186-A, US2023104118-A1
  • 发明人:   KIM H J, PARK H K, HAN H Y, PARK J S, LEE J K, KIM H, PARK H, HONG Y, PARK J, LEE J, LI Z
  • 专利权人:   GRAB ROOM CO LTD, GRAPSIL CO LTD, GRAPSIL CO LTD
  • 国际专利分类:   C01B032/05, C01B032/194, C01B032/21, C01B033/02, H01M010/052, H01M004/36, H01M004/38, H01M004/62, H01M004/04, H01M004/583, H01M004/66
  • 专利详细信息:   KR2244194-B1 26 Apr 2021 H01M-004/36 202139 Pages: 17
  • 申请详细信息:   KR2244194-B1 KR138027 23 Oct 2020
  • 优先权号:   KR138027, CN80024491

▎ 摘  要

NOVELTY - Producing a cathode active material including graphene-silicon complex comprises combining single or multiple silicon-containing particles on a single or multiple reduced graphene oxide sheets by electrostatic attraction, and alternately stacking with each other to form primary graphene-silicon complex, drying the graphene oxide sheet and the silicon precursor after wet mixing in an organic solvent, preparing primary graphene-silicon complex formed of silicon-containing particles stacked on the reduced graphene oxide sheet by heat treatment at 250-350 degrees C, adding precursor of conductive carbon including 1-10 wt.% amorphous carbon precursor based on total weight of secondary graphene-silicon complex to the primary graphene-silicon complex, firing in an inert atmosphere for preparing secondary graphene-silicon complex. USE - The cathode active material is useful in lithium secondary battery as power sources for mobile electronic devices including mobile phones, and large devices e.g. electric vehicles. ADVANTAGE - The cathode active material has excellent conductivity, excellent safety and durability. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) cathode active material prepared by above mentioned method; and (2) lithium secondary battery comprising cathode active material.