• 专利标题:   Repairing defects of graphene comprises subjecting composite fluid having reactive compound and supercritical fluid to impregnate graphene powder with in reactor containing graphene powder and separating fluid and powder, and adsorbing.
  • 专利号:   US2019352187-A1, EP3569572-A1, TW665161-B1, JP2019199398-A, TW201946872-A
  • 发明人:   LI Z, TU P, CHEN C, HUANG Y, LI Z Y, TU P M, CHEN C J, HUANG Y W
  • 专利权人:   XSENSE TECHNOLOGY CORP, XSENSE TECHNOLOGY CORP
  • 国际专利分类:   C01B032/194, C01B032/19, C01B032/196, H01M004/62
  • 专利详细信息:   US2019352187-A1 21 Nov 2019 C01B-032/194 201992 Pages: 16 English
  • 申请详细信息:   US2019352187-A1 US412582 15 May 2019
  • 优先权号:   TW116597

▎ 摘  要

NOVELTY - Repairing defects of graphene, comprises: introducing and subjecting a composite fluid having a reactive compound and a supercritical fluid to impregnate a graphene powder with in a reactor containing the graphene powder and conforming to a supercritical fluid environment, where the reactive compound is a compound comprising an element of carbon, hydrogen, nitrogen, silicon or oxygen to passivate and repair the defects of the graphene powder; and separating the composite fluid and the graphene powder, and adsorbing the graphene powder retained in the composite fluid by a molecular sieve. USE - The method is useful for repairing defects of graphene and producing graphene powder (claimed). ADVANTAGE - The method: increases graphene content from less than 80-99.95%; reduces the ratio of the defect of the graphene, increases the content of the graphene, and has less-layer graphene with high thermal conductivity and electrical conductivity; provides the graphene powder with good thermal conductivity and electrical conductivity; and is simple and low cost without any pollution problem thus environmental friendly. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for graphene powder comprising a graphene having at least one chemical bond consisting of nitrogen-hydrogen, carbon-hydrogen, carbon-oxygen, carbon-nitrogen, and carbon-silicon, and the graphene has 20 layers or less in number where the graphene powder has a 2D/G value of 0.3-0.6, and the graphene powder has a G/D value of 2.0-4.0, and the 2D/G value and the G/D value are obtained from an intensity ratio of a Raman shift 1351 wavenumber (D band), a Raman shift 1587 wavenumber (G band), and a Raman shift 2687 wavenumber (2D band) analyzed by a Raman spectroscopy.