• 专利标题:   Molecularly imprinted material on the surface of corn zearalenone functionalized graphene comprises using e.g. reduced graphene oxide as carrier, cyclododecyl 2,4-dihydroxybenzoate as template molecule and acetonitrile as porogen.
  • 专利号:   CN111909311-A
  • 发明人:   HAN Y, SUN C, WANG J, CHANG X
  • 专利权人:   NAT FOOD STRATEGIC RESERVES ADMIN
  • 国际专利分类:   B01J020/26, B01J020/30, C08F222/14, C08F226/06, C08F226/08, C08J009/26, C08J009/28, C08K003/04, C08L039/04
  • 专利详细信息:   CN111909311-A 10 Nov 2020 C08F-226/06 202000 Pages: 13 Chinese
  • 申请详细信息:   CN111909311-A CN10641149 06 Jul 2020
  • 优先权号:   CN10641149

▎ 摘  要

NOVELTY - Molecularly imprinted material on the surface of corn zearalenone (ZEN) functionalized graphene comprises using reduced graphene oxide (rGO) as carrier, cyclododecyl 2,4-dihydroxybenzoate (CDHB) as template molecule, 1-allylpiperazine (1-ALPP) as functional monomer, trimethyl trimethacrylate (TRIM) as cross-linking agent, 2,2'-azobisisobutyronitrile (AIBN) as initiator and acetonitrile as a porogen. USE - Used as molecularly imprinted material on the surface of corn zearalenone (ZEN) functionalized graphene. ADVANTAGE - The material has high adsorption capacity and good selectivity for ZEN; can be used for the separation and removal of ZEN and has broad application prospects. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing imprinted material comprising sequentially adding CDHB, 1-ALPP, TRIM, AIBN, and acetonitrile to the solvent, mixing, filling with nitrogen, deoxygenating, then sealing, irradiating with ultraviolet light for 24 hours or 60 degrees C water bath constant temperature reaction for 24 hours to prepare molecularly imprinted polymer, grinding the molecularly imprinted polymer through a 100-200 mesh sieve, using the eluent to remove CDHB, drying overnight at 40 degrees C to obtain the molecularly imprinted polymer with the template removed, preparing the molecularly imprinted material on the surface of zearalenone-functionalized graphene by GO and the molecularly imprinted polymer with the template removed by the water bath method.