• 专利标题:   Catalyst used for hydrolyzing e.g. cellulose, comprises graphene sheet comprising sheet formed by connecting carbon skeletons having carbon atoms bonded to each other in hexagonal shape, and having carboxyl group/sulfonic acid group.
  • 专利号:   WO2018190279-A1, JP2018176045-A
  • 发明人:   MAKOTO O, YOSHIAKI K, OKAI M, KURIHARA Y
  • 专利权人:   HITACHI CHEM CO LTD, HITACHI CHEM CO LTD
  • 国际专利分类:   B01J021/18, B01J035/02, B01J037/04, B01J037/08, C01B032/225, C13K001/02
  • 专利详细信息:   WO2018190279-A1 18 Oct 2018 B01J-021/18 201875 Pages: 33 Japanese
  • 申请详细信息:   WO2018190279-A1 WOJP014807 06 Apr 2018
  • 优先权号:   JP077289

▎ 摘  要

NOVELTY - A hydrolysis catalyst comprises a graphene sheet comprising a sheet formed by connecting carbon skeletons having carbon atoms bonded to each other in a hexagonal shape in a plane. The graphene sheets are laminated in 2-5 layers. In the graphene sheet, 1 or more carboxyl group and sulfonic acid group is bonded. The length of the shortest portion of the graphene sheet in a photograph taken by the transmission electron microscope is 1 mu m or more. USE - Catalyst is used for hydrolyzing cellulose and hemicellulose for producing monosaccharide (claimed). ADVANTAGE - The catalyst is environmentally-friendly, and enables efficient of hydrolyzing cellulose and hemicelluloses. The catalyst can be separated from hydrolyzed mixture by simple process. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) manufacture of hydrolysis catalyst, which involves mixing flaky graphite, sulfuric acid and hydrogen peroxide solutions, heat-treating resultant mixture at 500-1000 degrees C, cooling, and heat-treating at 500-1000 degrees C; (2) usage method of hydrolysis catalyst for producing monosaccharide, which involves hydrolyzing cellulose and/or hemicellulose in water, subjecting resultant solution to membrane filtration and separating the catalyst; and (3) device for manufacturing sugar-containing liquid.