• 专利标题:   Double-network nanocomposite polymer hydrogel for e.g. biomedicine comprises double-network hydrogel containing monomers, and nanoparticles e.g. graphene oxide, halloysite, carbon nanotube, pyrochlore, montmorillonite, and talcum powder.
  • 专利号:   CN103435951-A, CN103435951-B
  • 发明人:   NI Z, CHEN M, MA P, DONG W, HUANG C
  • 专利权人:   UNIV JIANGNAN
  • 国际专利分类:   C08F220/56, C08F220/58, C08K003/04, C08K003/34, C08K007/00, C08K009/00, C08L033/24, C08L033/26
  • 专利详细信息:   CN103435951-A 11 Dec 2013 C08L-033/26 201420 Pages: 6 Chinese
  • 申请详细信息:   CN103435951-A CN10408122 09 Sep 2013
  • 优先权号:   CN10408122

▎ 摘  要

NOVELTY - A double-network nanocomposite polymer hydrogel comprises double-network hydrogel and nanoparticles with weight ratio of 100:1-50 in which double-network hydrogel contains 1st network hydrogel containing monomer i.e. 2-acrylamido-2-methyl propanesulfonic acid, methacrylic acid, styrene sulfonic acid, vinyl sulfonic acid, methacrylic acid salt, styrene sulfonate, and/or vinyl sulfonate, and 2nd network hydrogel containing monomer i.e. acrylic acid and derivatives, methacrylic acid and derivatives, acrylamide and derivatives, N-vinyl formamide, vinyl pyridine, and/or N-vinyl pyrrolidone. USE - A double-network nanocomposite polymer hydrogel for biomedicine, agriculture, chemical industry, and mining. ADVANTAGE - Hydrogel has high compressive and tensile strength and excellent flexibility, and preparation method is simple. DETAILED DESCRIPTION - A double-network nanocomposite polymer hydrogel comprises double-network hydrogel and nanoparticles with weight ratio of 100:1-50 in which double-network hydrogel contains 1st network hydrogel containing monomer i.e. 2-acrylamido-2-methyl propanesulfonic acid, methacrylic acid, styrene sulfonic acid, vinyl sulfonic acid, methacrylic acid salt, styrene sulfonate, and/or vinyl sulfonate, and 2nd network hydrogel containing monomer i.e. acrylic acid and derivatives, methacrylic acid and derivatives, acrylamide and derivatives, N-vinyl formamide, vinyl pyridine, and/or N-vinyl pyrrolidone, and inorganic nanoparticles is graphene oxide, halloysite, carbon nanotube, pyrochlore, montmorillonite, talcum powder, beidellite, water pyroxene, silica, metahalloysite, cage-typed silsesquioxane, microcrystalline cellulose, graphene, oxidized carbon nanotube, hydroxyapatite, metal and oxides, and/or fullerene. An INDEPENDENT CLAIM is included for preparation of double-network nanocomposite polymer hydrogel which involves dissolving 1st network hydrogel monomer, crosslinking agent, and initiator in nanoparticle-containing aqueous dispersion, pouring mixed solution in silicone rubber mold, reacting at 50-80 degrees C for 6-20 hours to obtain 1st network hydrogel, dissolving 2nd network hydrogel, cross-linking agent, and initiator in water, adding obtained 1st network hydrogel, swelling for 24-30 hours, and reacting at 50-80 degrees C for 6-20 hours.