• 专利标题:   Preparing graphene quantum dot-doped nobel metal nanotube array by using constant current co-deposition useful in e.g. electrocatalysis comprises placing performing galvanostatic deposition and constant current co-deposition.
  • 专利号:   CN112007636-A
  • 发明人:   ZHANG L, LU P, MA W, ZHENG J, YU X, JIANG S
  • 专利权人:   UNIV ZHENGZHOU
  • 国际专利分类:   B01J023/42, B01J035/00, B01J035/04, B01J037/00, B01J037/34, H01M004/88, H01M004/92
  • 专利详细信息:   CN112007636-A 01 Dec 2020 B01J-023/42 202002 Pages: 11 Chinese
  • 申请详细信息:   CN112007636-A CN10869716 26 Aug 2020
  • 优先权号:   CN10869716

▎ 摘  要

NOVELTY - Preparing graphene quantum dot-doped nobel metal nanotube array by using constant current co-deposition comprises (a) placing the titanium sheet in a mixed aqueous solution containing zinc nitrate and ammonium nitrate at room temperature, using galvanostatic deposition to obtain a zinc oxide nanorod array at 70-90 degrees C, (b) placing the zinc oxide nanorod array in a mixed aqueous solution containing precious metals and graphene quantum dots, adjusting the pH to 3-6, using constant current co-deposition to simultaneously load precious metals and graphene quanta onto the zinc oxide nanorod array at room temperature and (c) statically placing the zinc oxide nanorod array loaded with precious metal nanoparticles and graphene quantum dots in a dilute sulfuric acid solution to dissolve and removing the zinc oxide template to obtain self-supporting graphene quantum dots doped with precious nobel nanotube array. USE - The array is useful in the fields of electrocatalysis and proton exchange membrane fuel cells. ADVANTAGE - The array: increase electrochemical active area by 30-90% and has high electrochemical active area. The method: is mild, green and high-efficiency; has simple preparation process, strong operability and is suitable for mass production.