• 专利标题:   Preparing sulfonated polysulfone polymer doped carboxylic acid sulfonated graphene hybrid membrane for removing calcium and magnesium ions in water, by preparing carboxylic acid sulfonated graphene, concentrating and reacting.
  • 专利号:   CN111318268-A
  • 发明人:   ZHANG L, QIAO L, ZHANG Y
  • 专利权人:   UNICORE MEMBRANE SCI TECHNOLOGY TIANJI
  • 国际专利分类:   B01J020/26, B01J020/28, B01J020/30, C02F001/28
  • 专利详细信息:   CN111318268-A 23 Jun 2020 B01J-020/26 202062 Pages: 10 Chinese
  • 申请详细信息:   CN111318268-A CN10143988 04 Mar 2020
  • 优先权号:   CN10143988

▎ 摘  要

NOVELTY - Method for preparing sulfonated polysulfone polymer doped carboxylic acid sulfonated graphene hybrid membrane involves (i) preparing the carboxylic acid sulfonated graphene through sulfonation reaction and carboxylation reaction, (ii) adding carboxylic acid sulfonated graphene powder to concentrated sulfuric acid and reacting at 90-180 degrees C for 6-12 hours, and (iii) adding the polysulfone polymer to the concentrated sulfuric acid solution of carboxylic acid sulfonated graphene obtained in step (ii), stirring the reaction to obtain uniform film casting solution, defoaming, scraping the film and placing it in the coagulation bath to obtain phase separation (A) film, washing and immersing in water and freeze-drying to obtain the sulfonated polysulfone polymer doped carboxylic acid sulfonated graphene hybrid film. USE - The method is useful for removing calcium and magnesium ions in water (claimed). ADVANTAGE - The method adopts one-pot braised film-making method, is simple and controllable to operate, low in cost, solves the problem of difficult recovery of the powder adsorbent and can quickly adsorb calcium and magnesium ions in water. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a sulfonated polysulfone polymer doped carboxyl group prepared using above-mentioned method.