• 专利标题:   Method for preparing graphene oxide and solvent resistant nanofiltration membrane, involves dispersing polymer of intrinsic microporosity in organic solution, followed by vacuum filtering microporous polymer composited on base film.
  • 专利号:   CN110152503-A
  • 发明人:   ZHANG G, HOU R, XU Z, MENG Q
  • 专利权人:   UNIV ZHEJIANG TECHNOLOGY
  • 国际专利分类:   B01D067/00, B01D069/02, B01D069/12, B01D071/02
  • 专利详细信息:   CN110152503-A 23 Aug 2019 B01D-071/02 201976 Pages: 7 Chinese
  • 申请详细信息:   CN110152503-A CN10255710 29 Mar 2019
  • 优先权号:   CN10255710

▎ 摘  要

NOVELTY - A graphene oxide and solvent resistant nanofiltration membrane preparing method involves dispersing uniformly polymer of intrinsic microporosity-1 in the organic solution A to obtain an organic solution of polymer of intrinsic microporosity-1, dispersing graphene oxide in water to obtain an aqueous solution of graphene oxide, and adding the aqueous solution of the graphene oxide to the solvent B, and stirring to obtain a graphene oxide mixture. The graphene oxide mixture is added to the organic solution of the polymer of intrinsic microporosity-1 to obtain a graphene oxide-polymer of intrinsic microporosity mixed solution, added solvent C to the graphene oxide-polymer of intrinsic microporosity mixed solution, stirred the mixture to obtain a dispersed graphene oxide-polymer of intrinsic microporosity solution, and vacuum filtered a microporous polymer composited on the base film. USE - Method for preparing graphene oxide and solvent resistant nanofiltration membrane. ADVANTAGE - The method enables preparing graphene oxide and solvent resistant nanofiltration membrane with uniform, simple and mild operation. DETAILED DESCRIPTION - A graphene oxide and solvent resistant nanofiltration membrane preparing method involves dispersing uniformly polymer of intrinsic microporosity-1 in the organic solution A to obtain an organic solution of polymer of intrinsic microporosity-1 at a concentration of 0.1-0.3 g/L, dispersing graphene oxide in water to obtain an aqueous solution of graphene oxide having a concentration of 0.1-0.3 g/L, and adding the aqueous solution of the graphene oxide to the solvent B, and uniformly stirring to obtain a graphene oxide mixture. The graphene oxide mixture is added to the organic solution of the polymer of intrinsic microporosity-1 to obtain a graphene oxide-polymer of intrinsic microporosity mixed solution in a mass ratio of 0.5-4:1, added solvent C to the graphene oxide-polymer of intrinsic microporosity mixed solution, stirred the mixture continuously to obtain a uniformly dispersed graphene oxide-polymer of intrinsic microporosity solution, and vacuum filtered a microporous polymer composited on the base film, where the organic solution A is tetrahydrofuran, chloroform, dichloromethane, the solvent B is a mixture of N,N-dimethylformamide, tetrahydrofuran, water, water and tetrahydrofuran, and the solvent C is N,N-dimethylformamide, tetrahydrofuran, water or a mixture of water and tetrahydrofuran.