• 专利标题:   Modified sodium titanium manganese phosphate anode material used in sodium ion battery, comprises inner core and carbon coating layer coated on surface of inner core, where inner core includes fluorine ion, chlorine ion, and bromine ion.
  • 专利号:   CN113422043-A, CN113422043-B
  • 发明人:   ZHAO J, XU C, LIU H
  • 专利权人:   INST PROCESS ENG CHINESE ACAD SCI
  • 国际专利分类:   H01M010/054, H01M004/485, H01M004/505, H01M004/58
  • 专利详细信息:   CN113422043-A 21 Sep 2021 H01M-004/485 202190 Pages: 14 Chinese
  • 申请详细信息:   CN113422043-A CN10812852 19 Jul 2021
  • 优先权号:   CN10812852

▎ 摘  要

NOVELTY - Modified sodium manganese titanium manganese phosphate anode material comprises inner core and the carbon coating layer on the surface of the inner core. The inner core is Na3+2 delta Ti1-deltaMn1+delta(PO4)3-xXn-3x/n, where the Xn-= fluorine ion (F-), chlorine ion (Cl-), bromine ion (Br-), sulfide ion (S2-), nitrogen ion (N3-), borate ion (BO3-), tetraborate ion (B4O72-), pyrophosphate (P2O74-) or sulfate ion (SO42-), x=0-1, but does not contain 0, and delta =0-0.5. USE - Modified sodium titanium manganese phosphate anode material used in sodium ion battery (claimed). ADVANTAGE - The modified titanium manganese phosphate anode material has improved electrochemical property. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the modified sodium titanium manganese phosphate anode material, which involves mixing the manganese source, titanium source, sodium source, phosphorus source, doped anion source, organic carbon source and solvent, stirring until the solvent evaporate completely to obtain the precursor, and calcining the obtained precursor to obtain the modified sodium titanium manganese phosphate anode material.