• 专利标题:   Preparing graphene conductive composite fibers comprises e.g. immersing the textile fiber in a silane coupling agent KH560 solution, drying the fiber to obtain a surfactant-modified textile fibers.
  • 专利号:   CN108085966-A
  • 发明人:   WU K, HE G
  • 专利权人:   HENAN XINYE TEXTILE CO LTD
  • 国际专利分类:   D06M101/06, D06M101/10, D06M101/12, D06M101/32, D06M101/34, D06M101/36, D06M011/74, D06M013/513
  • 专利详细信息:   CN108085966-A 29 May 2018 D06M-011/74 201840 Pages: 6 Chinese
  • 申请详细信息:   CN108085966-A CN11393601 21 Dec 2017
  • 优先权号:   CN11393601

▎ 摘  要

NOVELTY - Preparing graphene conductive composite fibers comprises (i) immersing the textile fiber in a 1-30% silane coupling agent KH560 solution for 2-3 hours and drying the fiber in an oven at 50-65 degrees C to obtain a surfactant-modified textile fibers, (ii) dipping the modified textile fiber into an aqueous solution containing graphene oxide or a derivative having a pH of 2-6 at 10-50 degrees C for 0.2-2 hours and drying the fabric, reducing the dried fabric impregnated with graphene oxide or a derivative using a 1-10 g/l reducing agent solution, washing with water and drying to obtain a conductive fabric covered with reduced graphene oxide or a derivative, (iii) preparing the graphene by a chemical reduction method of an aqueous graphene oxide solution prepared by Hummer's method, where the dispersant is used to obtain a uniform and stable dispersion of graphene and the concentration is 0.1-5% and (iv) soaking the textile fibers in the graphene dispersion for 2-3 hours and placing in a drying oven. USE - The method is useful for preparing graphene conductive composite fibers. ADVANTAGE - The method provides high yield and is simple. DETAILED DESCRIPTION - Preparing graphene conductive composite fibers comprises (i) immersing the textile fiber in a 1-30% silane coupling agent KH560 solution for 2-3 hours and drying the fiber in an oven at 50-65 degrees C to obtain a surfactant-modified textile fibers, (ii) dipping the modified textile fiber into an aqueous solution containing graphene oxide or a derivative having a pH of 2-6 at 10-50 degrees C for 0.2-2 hours and drying the fabric at 40-100 degrees C for 0.5-4 hours, reducing the dried fabric impregnated with graphene oxide or a derivative using a 1-10 g/l reducing agent solution, where the reducing temperature is 50-100 degrees C and the reducing time is 0.5-6 hours, washing with water and drying to obtain a conductive fabric covered with reduced graphene oxide or a derivative, (iii) preparing the graphene by a chemical reduction method of an aqueous graphene oxide solution prepared by Hummer's method, where the dispersant is used to obtain a uniform and stable dispersion of graphene and the concentration is 0.1-5% and (iv) soaking the textile fibers in the graphene dispersion for 2-3 hours and placing in a drying oven at 50-65 degrees C