• 专利标题:   Preparing lithium-sulfur battery with iron nitride nanoparticles grown in situ on reduced graphene oxide as a modified separator material, involves dispersing graphene in deionized water and marking it as solution A.
  • 专利号:   CN111211273-A
  • 发明人:   ZHANG D, YUE H, WANG X, MA C, CHEN G
  • 专利权人:   UNIV JILIN
  • 国际专利分类:   H01M010/0525, H01M010/058, H01M002/14, H01M002/16
  • 专利详细信息:   CN111211273-A 29 May 2020 H01M-002/14 202051 Pages: 11 Chinese
  • 申请详细信息:   CN111211273-A CN10030175 13 Jan 2020
  • 优先权号:   CN10030175

▎ 摘  要

NOVELTY - Preparing lithium-sulfur battery involves dispersing 200-250 mg graphene in 40-60 mL deionized water and marking it as solution A, dissolving 180-220 mg ferric nitrate nonahydrate and 100-140 mg urea in 15-30 mL deionized water, stirring uniformly and adding into solution A drop by drop, then, cooling the resulting mixed solution to room temperature after hydrothermal reaction, and washing and lyophilizing the product, finally, obtaining iron nitide-reduced graphene oxide (Fe2N/N-rGO) composite material after heat treatment at 700-800 degrees C for 2-4 hours in ammonia atmosphere, dissolving the Fe2N/N-rGO composite material and binder polyvinylidene fluoride in N-methylpyrrolidone at a ratio of 9-12:1, mixing uniformly, coating on one side surface of Celgard 2320, vacuum drying, and pressing into a wafer with a punching machine to obtain a Fe2N/N-rGO diaphragm. USE - Method for preparing lithium-sulfur battery. ADVANTAGE - The method provides product, which has excellent electrochemical performance, high specific capacity, stable cycle performance and good rate performance. DETAILED DESCRIPTION - Preparing lithium-sulfur battery involves dispersing 200-250 mg graphene in 40-60 mL deionized water and marking it as solution A, dissolving 180-220 mg ferric nitrate nonahydrate and 100-140 mg urea in 15-30 mL deionized water, stirring uniformly and adding into solution A drop by drop, then, cooling the resulting mixed solution to room temperature after hydrothermal reaction, and washing and lyophilizing the product, finally, obtaining iron nitide-reduced graphene oxide (Fe2N/N-rGO) composite material after heat treatment at 700-800 degrees C for 2-4 hours in ammonia atmosphere, dissolving the Fe2N/N-rGO composite material and binder polyvinylidene fluoride in N-methylpyrrolidone at a ratio of 9-12:1, mixing uniformly, coating on one side surface of Celgard 2320, vacuum drying, pressing into a wafer with a punching machine to obtain a Fe2N/N-rGO diaphragm, where load of Fe2N/N-rGO on the diaphragm as 0.2000.30 mg/cm2, mixing and dissolving elemental sulfur, conductive auxiliary agent and binder polyvinylidene fluoride in N-methylpyrrolidone, crusing, coating on aluminum foil, vacuum-drying and pressing into a disk as a positive electrode with a punch, where sulfur loading of the positive electrode as 1.5-1.7 mg/cm2, using lithium film as negative electrode, and then the half-cell of the Celgard2320 coated with Fe2N/N-rGO composite material faced the positive electrode to assemble the half-cell, thus obtaining the product.