• 专利标题:   Preparing flexible transparent conductive film based on micro-stereo lithography technology, involves embedding conductive network in flexible transparent polymer, and removing cured flexible transparent polymer from clean substrate.
  • 专利号:   CN112768141-A, CN112768141-B
  • 发明人:   CHEN X, WANG S, SHAO J, WANG C, ZHANG J, LI X, TIAN H
  • 专利权人:   UNIV XIAN JIAOTONG
  • 国际专利分类:   B33Y030/00, B33Y080/00, H01B013/00
  • 专利详细信息:   CN112768141-A 07 May 2021 H01B-013/00 202150 Pages: 14 Chinese
  • 申请详细信息:   CN112768141-A CN11640019 31 Dec 2020
  • 优先权号:   CN11640019

▎ 摘  要

NOVELTY - Preparing flexible transparent conductive film based on micro-stereolithography technology involves placing clean substrate on printing platform of micro-stereolithography 3D printing system and fixing, and then using soluble photosensitive resin as 3D printing material to print groove structure on clean substrate of soluble photosensitive resin mold; using medical spatula to scrape conductive paste into groove structure of soluble photosensitive resin mold, filling groove, and then placing on 60-80 degrees C drying table for heating 5-15 minutes, solidify conductive paste to form conductive network embedded in soluble photosensitive resin mold; placing soluble photosensitive resin mold with conductive network in 1-3 wt.% sodium hydroxide (NaOH) solution and soaking for 1.5-2.5 hours to dissolve soluble photosensitive resin mold to obtain conductive network which is exposed on surface of clean substrate, rinsing residual NaOH solution gently with deionized water. USE - Method for preparing flexible transparent conductive film based on micro-stereo lithography technology. ADVANTAGE - The method enables to solve limitation of using conductive slurry and improves conductive film performance by structure design; is cost-effective, simple technique, wide applicability, large scale, and large area manufacturing. DETAILED DESCRIPTION - Preparing flexible transparent conductive film based on micro-stereolithography technology involves placing clean substrate on printing platform of micro-stereolithography 3D printing system and fixing, and then using soluble photosensitive resin as 3D printing material to print groove structure on clean substrate of soluble photosensitive resin mold; using medical spatula to scrape conductive paste into groove structure of soluble photosensitive resin mold, filling groove, and then placing on 60-80 degrees C drying table for heating 5-15 minutes, solidify conductive paste to form conductive network embedded in soluble photosensitive resin mold; placing soluble photosensitive resin mold with conductive network in 1-3 wt.% sodium hydroxide (NaOH) solution and soaking for 1.5-2.5 hours to dissolve soluble photosensitive resin mold to obtain conductive network which is exposed on surface of clean substrate, rinsing residual NaOH solution gently with deionized water, and placing on baking table at 60-80 degrees C for heating 5-15 minutes to dry conductive network; placing clean substrate with conductive network on homogenizer, spin-coating 3-5 mL flexible transparent polymer, spin-coating parameter is low speed 600-700 radian/minute, 10-12 seconds, high speed is 1000-1200 radian/minute, 30-40 seconds, and then placing in vacuum drying oven to vacuum for 10-15 minutes, where conductive network is completely embedded in flexible transparent polymer, then placing in vacuum drying oven at 75-85 degrees C and heating for 1-2 hours to cure flexible transparent polymer; peeling off cured flexible transparent polymer from clean substrate, where conductive network is completely embedded in flexible transparent polymer accompanied by flexible transparent polymer which is removed from clean substrate together to form flexible transparent conductive film. DESCRIPTION OF DRAWING(S) - The drawing shows a flowchart of method for preparing flexible transparent conductive film based on micro-stereolithography technology. (Drawing includes non-English language text).