• 专利标题:   Preparing a oxidation catalyst, comprises e.g. using aqueous solution containing boron and phosphorus to impregnate the carbonaceous material, drying and performing first roasting to obtain boron and phosphorus-doped carbon carrier and mixing with active metal component compound solution.
  • 专利号:   CN115722215-A
  • 发明人:   ZONG B, RONG J, DU Z, CHEN G, SUN Q, ZHAO H, ZHENG L
  • 专利权人:   RES INST PETROLEUM PROCESSING SINOPEC, CHINA PETROLEUM CHEM CORP
  • 国际专利分类:   B01J021/18, B01J027/14, B01J027/185, C07D307/68
  • 专利详细信息:   CN115722215-A 03 Mar 2023 B01J-021/18 202325 Chinese
  • 申请详细信息:   CN115722215-A CN10991169 26 Aug 2021
  • 优先权号:   CN10991169

▎ 摘  要

NOVELTY - Preparing a oxidation catalyst, comprises (1) using an aqueous solution containing boron and phosphorus to impregnate the carbonaceous material, and then performing the first roasting in an inert gas after drying to obtain a boron and phosphorus-doped carbon carrier, (2) mixing the boron and phosphorus doped carbon carrier with the active metal component compound solution to obtain a first mixture, and (3) performing first drying and first reduction on the first mixture. USE - The method is useful for preparing a oxidation catalyst. ADVANTAGE - The method: can ensure excellent catalytic activity and stability of the catalyst, and can catalyze the 2,5-furandicarboxylic acid with high selectivity under an alkali-free condition. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: a oxidation catalyst, comprising a carbon support doped with boron and phosphorus and an active metal component, where the specific surface area of the carbon carrier doped with boron and phosphorus is 200-2500 m/g. In the carbon carrier doped with boron and phosphorus, the amount of boron is 0.01-5 wt.%, the amount of phosphorus is 0.01-5 wt.%, and the amount of oxygen is 3-13 wt.% based on the amount of the oxidation catalyst, and the content of the active metal component is 1-40 wt.%; and2 a preparing a 2,5-furandicarboxylic acid, comprising (a) dissolving the 5-hydroxymethylfurfural in water to obtain 5-hydroxymethylfurfural solution, and (b) adding oxidation catalyst into resultant solution and carrying out oxidation reaction in the presence of oxygen.