• 专利标题:   Preparing graphene modified plastic pipe, by mixing aqueous dispersion of graphene oxide with colloidal solution of layered clay, melting tin powder, mixing with polyethylene, coupling agent, dispersant and stabilizer, extruding and cutting.
  • 专利号:   CN111286103-A
  • 发明人:   CHEN Q, ZAN H
  • 专利权人:   CHENGDU NEW KELI CHEM ENG SCI TECHNIC
  • 国际专利分类:   C08K013/06, C08K003/04, C08K003/34, C08K007/00, C08K009/02, C08K009/12, C08L023/06, C08L071/02
  • 专利详细信息:   CN111286103-A 16 Jun 2020 C08L-023/06 202056 Pages: 7 Chinese
  • 申请详细信息:   CN111286103-A CN10810355 23 Jul 2018
  • 优先权号:   CN10810355

▎ 摘  要

NOVELTY - Method for preparing graphene modified high-barrier gas-specific plastic pipe, involves (i) mixing aqueous dispersion of graphene oxide with colloidal solution of layered clay, adsorbing graphene oxide by the colloid, reducing the graphene oxide by hydrazine hydrate under microwave-assisted conditions, performing suction filtration, washing and drying the filter residue, where the graphene forms an intercalation substance with clay, (ii) melting tin powder under protection of nitrogen, adding graphene and clay intercalate, uniformly dispersing, spraying to obtain fine powder, completely mixing with polyethylene, coupling agent, dispersant and stabilizer in a high-speed mixer, and extruding by a screw extruder to obtain a tube blank, and (iii) quickly cooling and cutting the extruded tube blank. USE - The method is useful for preparing graphene modified high-barrier gas-specific plastic pipe (claimed). ADVANTAGE - The method effectively isolates the agglomeration, so that the graphene is uniformly dispersed in the matrix resin, and improves diffusion resistance of the plastic pipe.