• 专利标题:   Preparing graphene-iron oxide-hydroxide nanocrystalline lithium ion battery anode material under in situ growth condition comprises e.g. adding graphene oxide into deionized water and adding soluble divalent iron and post-processing.
  • 专利号:   CN106356525-A, CN106356525-B
  • 发明人:   CAO L, QI H, LI J, HUANG J, DANG H, CHENG Y, JIE Y, LI C
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   C01G049/02, H01M010/0525, H01M004/1391, H01M004/52
  • 专利详细信息:   CN106356525-A 25 Jan 2017 H01M-004/52 201720 Pages: 8 Chinese
  • 申请详细信息:   CN106356525-A CN10729937 25 Aug 2016
  • 优先权号:   CN10729937

▎ 摘  要

NOVELTY - Preparing graphene-iron oxide-hydroxide nanocrystalline lithium ion battery anode material under in situ growth condition comprises e.g. (i) adding graphene oxide into deionized water and mixing to obtain suspension, (ii) adding the soluble divalent iron salt to the suspension to obtain mixture having a ferrous ion concentration of 0.01-0.5 mol/l, stirring and adjusting the pH to 3-5 to obtain precursors, (iii) pouring the precursor into hydrothermal reactor and sealing the reactor, then raising the reaction temperature to 70-150 degrees C for 6-12 hours, washing and drying. USE - The method is useful for preparing graphene-iron oxide-hydroxide nanocrystalline lithium ion battery anode material under in situ growth condition (claimed). ADVANTAGE - The graphene-iron oxide-hydroxide nanocrystalline lithium ion battery anode material improves the conductivity. DETAILED DESCRIPTION - Preparing graphene-iron oxide-hydroxide nanocrystalline lithium ion battery anode material under in situ growth condition comprises (i) adding graphene oxide into deionized water and mixing to obtain the suspension having a concentration of 0.5-2 mg/ml, (ii) adding the soluble divalent iron salt to the suspension to obtain mixture having a ferrous ion concentration of 0.01-0.5 mol/l, stirring the resulting mixture for 10-60 minutes, and then adjusting the pH to 3-5 to obtain the precursors, (iii) pouring the precursor into hydrothermal reactor and sealing the reactor, then reacting at 40-60 degrees C for 30-60 minutes, then raising the reaction temperature to 70-150 degrees C for 6-12 hours, washing and drying at room temperature to obtain final product.