• 专利标题:   High flame retardant biomass-based modified polylactic acid film material comprises DL-lactide, catalyst, crosslinking agent, phytic acid modified graphene, chitosan, and melamine.
  • 专利号:   CN111393814-A
  • 发明人:   GAO S
  • 专利权人:   GAO S
  • 国际专利分类:   B01J019/00, B01J019/28, C01B032/194, C08G063/08, C08G063/85, C08J005/18, C08K013/06, C08K003/04, C08K005/1515, C08K005/3492, C08K009/04, C08L005/08, C08L067/04
  • 专利详细信息:   CN111393814-A 10 Jul 2020 C08L-067/04 202063 Pages: 11 Chinese
  • 申请详细信息:   CN111393814-A CN10334384 24 Apr 2020
  • 优先权号:   CN10334384

▎ 摘  要

NOVELTY - High flame retardant biomass-based modified polylactic acid film material comprises 75-88 pts. wt. DL-lactide, 0.5-1 pts. wt. catalyst, 4.5-8 pts. wt. crosslinking agent, 2-5 pts. wt. phytic acid modified graphene, 3-7 pts. wt. chitosan, and 2-4 pts. wt. melamine. USE - Used as a high flame retardant biomass-based modified polylactic acid film material. ADVANTAGE - The method improves compatibility and enhances the flame retardant properties of film. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing high flame-retardant biomass-based modified polylactic acid film material comprising (1) adding 2-5 pts. wt. phytic acid modified graphene to ethanol solvent, performing uniform ultrasonic dispersion, adding 2-4 pts. wt. melamine, heating to 85-110 degrees C, reacting for 5-10 hours, removing the solvent, washing and drying to prepare phytic acid melamine salt modified graphene, (2) adding phytic acid melamine salt modified graphene and 3-7 pts. wt. chitosan to the acetic acid solution with concentration of 1-4%, heating to 40-50 degrees C, stirring at constant speed for 1-2 hours, adding sodium hydroxide to adjust the solution to 8-9, adding 4.5-8 pts. wt. crosslinking agent epichlorohydrin, heating to 70-80 degrees C, reacting for 5-8 hours, vacuum drying the solution to remove the solvent, adding distilled water solvent for centrifugal washing to prepare phytic acid-chitosan crosslinked biomass-based graphene, and (3) adding biomass-based graphene to the dimethyl sulfoxide solvent, heating to 90-120 degrees C under nitrogen atmosphere and stirring evenly, adding 75-88 pts. wt. DL-lactide and 0.5-1 pts. wt. catalyst stannous octoate, reacting for 20-25 hours, cooling the solution, adding distilled water until there is a large amount of precipitation, filtering, washing, drying, placing solid product n a twin screw extruder, melting, blending at 160-180 degrees C, maintaining discharge temperature at 190-210 degrees C, and casting into film. DESCRIPTION OF DRAWING(S) - The drawing shows a front view of the kettle heating box.