• 专利标题:   Preparing paraquat by mixing pyridine and methanol, dripping methyl chloride, carrying out pyridine alkylation reaction and dimerization reaction, removing impurities, adding beating water, acid solution, homogeneous catalyst, feeding liquid chlorine, reacting, filtering and separating catalyst.
  • 专利号:   CN115448872-A
  • 发明人:   HUO M, FU S, WU C, ZHANG L, ZHANG Z, YU J
  • 专利权人:   ANHUI GUOXING BIOCHEM CO LTD
  • 国际专利分类:   B01J027/10, B01J027/122, B01J027/128, C07D213/127, C07D213/22
  • 专利详细信息:   CN115448872-A 09 Dec 2022 C07D-213/22 202312 Chinese
  • 申请详细信息:   CN115448872-A CN11156926 21 Sep 2022
  • 优先权号:   CN11156926

▎ 摘  要

NOVELTY - A process for preparing paraquat by homogeneous catalytic oxidation of amethyst comprises mixing pyridine and methanol, dripping methyl chloride, generating N-picoline chloride through pyridine alkylation reaction, generating 1,1-dimethyl-4,4-dihydrobipyridine through dimerization reaction, washing, removing impurities, adding beating water, acid solution and homogeneous catalyst under the condition of stirring at 600-1000 rpm, feeding liquid chlorine and stirring for reacting, filtering, separating the homogeneous catalyst and obtaining paraquat solution. USE - The process is used for preparing paraquat by homogeneous catalytic oxidation of amethyst. ADVANTAGE - The process is carried out under mild conditions, the yield of the product is high, the operation is convenient, the catalyst and the mother liquor can be recycled many times, which can meet the needs of industrial production, greatly reduces the production cost, reduces the material energy consumption, ensures clean production, reduces environmental pollution, and the process meets the requirements of energy saving and environmental protection.