• 专利标题:   Preparing anode material of graphene/alumina coated lithium ion battery involves adding graphite and potassium perchlorate in reaction vessel, adding concentrated acid, heating, stirring, filtering, washing, and processing ultrasonically.
  • 专利号:   CN106410151-A, CN106410151-B
  • 发明人:   QU Y, WANG W
  • 专利权人:   HEFEI GUOXUAN HIGH TECH POWER SOURCE CO, HEFEI GUOXUAN HIGH TECH POWER SOURCE CO
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/48, H01M004/587
  • 专利详细信息:   CN106410151-A 15 Feb 2017 H01M-004/36 201720 Pages: 7 Chinese
  • 申请详细信息:   CN106410151-A CN10964423 28 Oct 2016
  • 优先权号:   CN10964423

▎ 摘  要

NOVELTY - Preparing anode material of graphene/alumina coated lithium ion battery involves adding graphite and potassium perchlorate in a ratio of 1:4-12 in reaction vessel. Concentrated acid is added to the mixture. The ratio of the volume of concentrated acid and mass of the graphite is 60-180:1. The mixture is heated at 50-80 degrees C and stirred for 5-15 minutes. The reaction product is filtered, washed and processed ultrasonically to obtain graphene oxide acidic solution. The graphene oxide acidic solution is obtained by adding aluminum powder and graphite in a ratio of 3-9:1. USE - Method used for preparing anode material of graphene/alumina coated lithium ion battery (claimed). ADVANTAGE - The method enables to prepare anode material of lithium ion battery that has good processing performance, rate performance and cycle performance and safety performance, in a simple, quick, reaction and continuous manner that avoids introduction of impurity. DETAILED DESCRIPTION - Preparing anode material of graphene/alumina coated lithium ion battery involves adding graphite and potassium perchlorate in a ratio of 1:4-12 in reaction vessel. Concentrated acid is added to the mixture. The ratio of the volume of concentrated acid and mass of the graphite is 60-180:1. The mixture is heated at 50-80 degrees C and stirred for 5-15 minutes. The reaction product is filtered, washed and processed ultrasonically to obtain graphene oxide acidic solution. The graphene oxide acidic solution is obtained by adding aluminum powder and graphite in a ratio of 3-9:1. The mixture is stirred 0.3-2 hours and aqueous ammonia is added dropwise with stirring and precipitated. The ratio of aqueous ammonia solution and aluminum powder is 3-5:1. Hydrolyzing acid liquid is added dropwise to the filtrate to precipitate and aged to form graphene/aluminium oxide sol. Alumina sol is added into the graphene/lithium ion battery anode material and heated to 40-80 degrees C, stirred and reacted for 0.5-1.5 hours to obtain the graphene/oxide lithium ion battery anode material precursor. The graphene/oxide lithium ion battery anode material precursor is crushed and placed under an inert gas atmosphere for 3-9 hours to obtain the graphene/alumina-coated anode material of lithium ion battery.