• 专利标题:   Producing 3-chloro-1,2-propanediol using graphene oxide catalyst modified by acetic anhydride involves using solid acetic anhydride modified graphene oxide (AGO) as catalyst, and adding hydrochloric acid and glycerin to reaction kettle.
  • 专利号:   CN112299952-A
  • 发明人:   WANG X, YANG Y
  • 专利权人:   JIAXING RUNBO CHEM TECHNOLOGY CO LTD
  • 国际专利分类:   B01J031/06, C07C029/62, C07C031/36
  • 专利详细信息:   CN112299952-A 02 Feb 2021 C07C-029/62 202124 Pages: 5 Chinese
  • 申请详细信息:   CN112299952-A CN11223200 05 Nov 2020
  • 优先权号:   CN11223200

▎ 摘  要

NOVELTY - Producing 3-chloro-1,2-propanediol using graphene oxide catalyst modified by acetic anhydride involves using solid acetic anhydride modified graphene oxide (AGO) as a catalyst. The hydrochloric acid and glycerin are added to the reaction kettle, and heated to 50-110 degrees C in a nitrogen atmosphere. The reaction is stirred for 2-10 hours, and the temperature is lowered to 30-60 degrees C. Then the catalyst and the reaction liquid are separated by centrifugation. The reaction liquid is rectified under reduced pressure to obtain the product that is 3-chloro-1,2-propanediol. USE - Method for producing 3-chloro-1,2-propanediol using graphene oxide catalyst modified by acetic anhydride. ADVANTAGE - The process is simple, and the catalyst can be recycled and regenerated. The conversion rate of the reactant glycerol can reach more than 95%, and the selectivity of the product 3 chloro 1,2 propylene glycol can reach more than 80%.