• 专利标题:   Graphene/polylactic acid composite useful as functional material e.g. antistatic material and electromagnetic-shielding material, comprises graphene, polyethylene glycol, and polylactic acid, in weight ratio of preset range.
  • 专利号:   CN103804661-A, CN103804661-B
  • 发明人:   HU X, DAI J, ZHANG H, WEI R, HE Y
  • 专利权人:   YANCHENG JINGHUA NEW MATERIAL TECHNOLOGY, CHENGDU DIANKE HUAQING TECHNOLOGY CO LTD
  • 国际专利分类:   C08G063/08, C08G063/66, C08G063/78, C08K003/04, C08L067/00, C08L067/04, C08L071/08
  • 专利详细信息:   CN103804661-A 21 May 2014 C08G-063/08 201447 Pages: 11 Chinese
  • 申请详细信息:   CN103804661-A CN10029502 22 Jan 2014
  • 优先权号:   CN10029502

▎ 摘  要

NOVELTY - A graphene/polylactic acid composite comprises 0.01-10 wt.% graphene, 1-20 wt.% polyethylene glycol, and remaining polylactic acid. USE - Graphene/polylactic acid composite is useful as functional material e.g. antistatic material, electromagnetic-shielding material, and conductive carpet. ADVANTAGE - The graphene/polylactic acid composite has excellent conductivity, mechanical property, thermal stability, and hydrolysis resistance. The composite can be prepared by a simple and easy method. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of graphene/polylactic acid composite, which involves adding graphene or graphene oxide to 50-90 wt.% L-lactic acid aqueous solution, dispersing to obtain a mixed liquid, mixing the mixed liquid under inert gas atmosphere at 0.1-10 kPa and 100-180 degrees C for 1-5 hours, adding a mixture of catalyst and polyethylene glycol, reacting at 120-220 degrees C, melt-polycondensing for 4-30 hours to obtain an intermediate, crystallizing the intermediate for 0.5-5 hours at 90-150 degrees C, and solid-phase polymerizing the crystals at 0.05-2 kPa and 130-170 degrees C under inert gas atmosphere for 8-100 hours. The mass ratio of graphene or graphene oxide and L-lactic acid is 1:10-8000. The mass ratio of catalyst, polyethylene glycol, and mixed liquid is 1:1-20:50-100. The catalyst is p-toluenesulfonic acid and/or stannous chloride.