• 专利标题:   Degradable copolyester composition used as antistatic biodegradable film material for preparing electronic packaging bag film, comprises degradable copolyester, antistatic agent including edge-modified graphene, where degradable copolyester is aliphatic aromatic copolyester.
  • 专利号:   CN115637026-A
  • 发明人:   ZHANG Z, ZHANG L, WANG X, GAO D, ZHANG T, ZHENG C, SONG Z, XU Y, ZHU G, LV M, GUO P
  • 专利权人:   CHINA PETROLEUM CHEM CORP BEIJING CHEM, CHINA PETROLEUM CHEM CORP
  • 国际专利分类:   C08J005/18, C08K003/04, C08K009/00, C08K009/02, C08L067/02
  • 专利详细信息:   CN115637026-A 24 Jan 2023 C08L-067/02 202317 Chinese
  • 申请详细信息:   CN115637026-A CN10814267 19 Jul 2021
  • 优先权号:   CN10814267

▎ 摘  要

NOVELTY - Degradable copolyester composition comprises 100 pts. wt. degradable copolyester, 0.01-10 pts. wt. antistatic agent, preferably, 0.05-5 pts. wt. antistatic agent, more preferably, 0.1-1 pts. wt. antistatic agent. The antistatic agent is an edge-modified graphene. The edge-modified graphene has average sheet diameter is 2-30 µm, preferably, 5-15 µm. The average aspect ratio is 600-10000:1, preferably 1200-4500:1, more preferably 1500-3800:1. The electrical conductivity is 200-800 seconds/meter, preferably, 300-600 seconds/meter. The oxygen content in terms of oxygen element in the edge-modified graphene, is 3-30 at%, preferably, 5-18 at%. The hydrogen content calculated as hydrogen element is 1-10 at%, preferably, 3-8 at%. USE - Degradable copolyester composition used as antistatic biodegradable material for preparing electronic packaging bag film (all claimed). ADVANTAGE - The degradable copolyester composition has good mechanical property, easy opening, good antistatic properties, and biodegradable characteristics. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: 1. an antistatic biodegradable film material, which comprises: a degradable copolyester composition, and 1-50 pts. wt. film auxiliary agent, preferably, 2-22 pts. wt. film auxiliary agent, with the weight of the degradable copolyester composition being 100 pts wt., where film auxiliary agent includes slip agent, nucleating agent, antioxidant and degradable resin; and 2. a method for preparing antistatic biodegradable film material, which involves: extruding and granulating after mixing the degradable copolyester, antistatic agent, film auxiliary agent and optional compatibilizer, to obtain the antistatic biodegradable film material, or mixing degradable copolyester, granulating with an optional antioxidant to obtain a base resin, mixing with an antistatic agent, mixing slip agent, nucleating agent, compatibilizer and degradable resin, extruding, and granulating to prepare the antistatic biodegradable film material; and 3. an antistatic biodegradable film, which is: prepared from antistatic biodegradable film material.