• 专利标题:   Composite lithium-sulfur battery positive electrode material used in battery positive electrode, comprises reduced graphene oxide, cobalt-nickel-phosphorus quantum dots, and cobalt-nickel-phosphorus-reduced graphene oxide loaded sulfur.
  • 专利号:   CN112786831-A, CN112786831-B
  • 发明人:   REN M, XIAO T, YI F, LIU W, YANG M
  • 专利权人:   UNIV QILU TECHNOLOGY
  • 国际专利分类:   H01M010/052, H01M004/04, H01M004/133, H01M004/136, H01M004/139, H01M004/36, H01M004/58, H01M004/583
  • 专利详细信息:   CN112786831-A 11 May 2021 H01M-004/04 202150 Pages: 8 Chinese
  • 申请详细信息:   CN112786831-A CN10338968 30 Mar 2021
  • 优先权号:   CN10338968

▎ 摘  要

NOVELTY - Cobalt-nickel-phosphorus-reduced graphene oxide/sulfur composite lithium-sulfur battery positive electrode material comprises reduced graphene oxide which is a three-dimensional carbon material conductive network, cobalt-nickel-phosphorus quantum dots attached to the reduced graphene oxide sheet layer, and cobalt-nickel-phosphorus-reduced graphene oxide loaded sulfur. USE - The cobalt-nickel-phosphorus-reduced graphene oxide/sulfur composite lithium-sulfur battery positive electrode material is used in lithium-sulfur battery positive electrode with adsorption, catalysis and high conductivity characteristics. ADVANTAGE - The lithium-sulfur battery positive electrode material accelerates the oxidation-reduction reaction. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing cobalt-nickel-phosphorus-reduced graphene oxide/sulfur composite lithium-sulfur battery positive electrode material, which involves (i) mixing graphene oxide, cobalt salt, nickel salt, urea and ethylene glycol, stirring, reacting in a high-pressure reaction kettle, centrifuging, vacuum-drying, and calcining to obtain a cobalt-nickel-doped graphene precursor body, (ii) placing the precursor obtained in step (i) and sodium hypophosphite in a tubular furnace and calcining under an inert gas to obtain cobalt-nickel-phosphorus-reduced graphene oxide, (iii) mixing the cobalt-nickel-phosphorus-reduced graphene oxide obtained in step (ii) with sulfur, uniformly grinding, and annealing in an inert atmosphere to prepare a cobalt-nickel-phosphorus-reduced graphene oxide/sulfur composite lithium-sulfur battery positive electrode material, in which sulfur is uniformly supported on cobalt-nickel-phosphorus-reduced graphene oxide.