• 专利标题:   Manufacture of reduced graphene oxide involves reacting solid hydrazine compound or its derivative with carbon dioxide, using obtained hydrazine compound as reducing agent for reducing graphene oxide.
  • 专利号:   WO2014077602-A1, KR2014062655-A, KR1554170-B1, US2015344311-A1, US9527744-B2
  • 发明人:   HUR N H, LEE B, LEE K H
  • 专利权人:   UNIV SOGANG RES FOUND, HUR N H, LEE B, LEE K H
  • 国际专利分类:   C01B031/02, C07C243/10, C01B031/04, B82Y040/00
  • 专利详细信息:   WO2014077602-A1 22 May 2014 C01B-031/02 201438 Pages: 35
  • 申请详细信息:   WO2014077602-A1 WOKR010349 14 Nov 2013
  • 优先权号:   KR128862

▎ 摘  要

NOVELTY - A solid hydrazine compound (I) or its derivative is reacted with a carbon dioxide to obtain hydrazine compound (II) or (III). The obtained hydrazine compound (II) or (III) is used as reducing agent for reducing graphene oxide. Thus, the manufacture of reduced graphene oxide is enabled. USE - Manufacture of reduced graphene oxide (claimed). ADVANTAGE - The method enables economical and environmentally-friendly manufacture of graphene oxide having excellent purity, stability and conductivity, by a simple process. DETAILED DESCRIPTION - A solid hydrazine compound of formula (I) or its derivative is reacted with a carbon dioxide to obtain hydrazine compound of formula (II) or (III). The obtained hydrazine compound of formula (II) or (III) is used as reducing agent for reducing graphene oxide. Thus, the manufacture of reduced graphene oxide is enabled. R1,R2=H,1-30C optionally substituted aliphatic hydrocarbyl, optionally substituted 3-30C aliphatic cyclic group, 3-30C aliphatic heterocyclyl, 6-30C aromatic ring group containing Si, O, S, Se, N, P, or As, 1-30C aliphatic hydrocarbyl containing Si, O, S, Se, N, P, or As, 3-30C aliphatic hydrocarbyl containing Si, O, S, Se, N, P, or As, or 6-30C heterocyclyl containing Si, O, S, Se, N, P, or As.