• 专利标题:   Graphene structure-type molybdenum sulfide catalyst comprises active component comprising metal of cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum and/or copper, and molybdenum sulfide.
  • 专利号:   CN106111162-A, CN106111162-B
  • 发明人:   JI N, DIAO X, LIANG C, SONG J, LIU Q, SONG C
  • 专利权人:   UNIV TIANJIN, UNIV TIANJIN
  • 国际专利分类:   B01J027/051, B01J037/08
  • 专利详细信息:   CN106111162-A 16 Nov 2016 B01J-027/051 201709 Pages: 9 Chinese
  • 申请详细信息:   CN106111162-A CN10450484 17 Jun 2016
  • 优先权号:   CN10450484

▎ 摘  要

NOVELTY - A graphene structure-type molybdenum sulfide catalyst comprises 2-95 wt.% active component comprising 0.05-30 wt.% metal and 1-95 wt.% molybdenum sulfide, and porous carrier. The metal is cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum and/or copper. USE - Graphene structure-type molybdenum sulfide catalyst. ADVANTAGE - The method has simple operation, and high yield and repeatability. The catalyst has low cost. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of graphene structure-type molybdenum sulfide catalyst comprising dissolving coordination compound with molybdenum active component and thiuram accelerant in organic solvent, heating under protection of inert atmosphere at 50-120 degrees C, refluxing for 2-10 hours, standing overnight at room temperature for 2-5 hours to obtain precipitate, filtering, washing with pentane, drying at 100-160 degrees C to obtain complex precursor soluble salt, soaking on carrier, heating, and decomposing under argon gas or nitrogen gas atmosphere at 300-800 degrees C for less than 4 hours.