• 专利标题:   Electrochemical cell, such as primary battery or secondary battery, comprises first electrode comprising alkali metal and/or alkaline earth metal, second electrode, and halogenated compound comprising sulfur pentafluoride group associated with conjugated system.
  • 专利号:   US2022367885-A1
  • 发明人:   GAO H, GALLANT B
  • 专利权人:   MASSACHUSETTS INST TECHNOLOGY
  • 国际专利分类:   H01M010/0567, H01M004/133, H01M004/134, H01M006/16
  • 专利详细信息:   US2022367885-A1 17 Nov 2022 H01M-006/16 202202 English
  • 申请详细信息:   US2022367885-A1 US679031 23 Feb 2022
  • 优先权号:   US153331P, US679031

▎ 摘  要

NOVELTY - Electrochemical cell (10) comprises a first electrode (12) comprising an alkali metal and/or an alkaline earth metal (14); a second electrode (16); and a halogenated compound (11) comprising at least one sulfur pentafluoride group associated with a conjugated system. USE - Electrochemical cell, such as primary battery or a secondary battery (claimed). ADVANTAGE - The electrochemical cells exhibit high energy densities and capacities. The close-to-full dehalogenation of the halogenated compounds can be achieved at practical discharge conditions (e.g., 0.3 mA/cm2), yielding between 8-15 electron stransfers per molecule and relatively high discharge potentials (e.g., 2.6 Volts). As a result, high achievable specific energies (e.g., up to 2565 Wh/kg reactant) and total capacities (e.g., up to 1140 mAh/g reactant) are attainable, making the halogenated compounds a strong competitor as electrodes in high-energy batteries (e.g., primary batteries). The structure of the halogenated compounds additionally allows for multiple types of modification (e.g., ring structure, substituent type and position, haloalkene chain length, halogenated group species), which can directly affect the reduction of these molecules. The use of halogenated compound in an electrochemical cell provides an enhanced electrochemical performance, such as an increased specific energy. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic view of an electrochemical cell. 10Electrochemical cell 11Halogenated compound 12First electrode 14Metal 16Second electrode