• 专利标题:   Double-carbon modified polyanionic sodium-ion battery cathode material useful in preparation of sodium ion batteries comprise sodium-manganese-chromium phosphate and carbon-based material modified on surface of sodium-manganese-chromium phosphate.
  • 专利号:   CN114649520-A
  • 发明人:   CHEN S, YU C, YIN Y, ZHAO H, BAI Y, SONG C, LI S
  • 专利权人:   UNIV HENAN
  • 国际专利分类:   B82Y030/00, B82Y040/00, H01M010/054, H01M004/04, H01M004/36, H01M004/58, H01M004/62
  • 专利详细信息:   CN114649520-A 21 Jun 2022 H01M-004/36 202267 Chinese
  • 申请详细信息:   CN114649520-A CN10331290 31 Mar 2022
  • 优先权号:   CN10331290

▎ 摘  要

NOVELTY - Double-carbon modified polyanionic sodium-ion battery cathode material, comprises sodium-manganese-chromium phosphate and carbon-based material modified on the surface of sodium-manganese-chromium phosphate and carbon-based material b embedded in sodium-manganese-chromium phosphate. USE - The double-carbon modified polyanionic sodium-ion battery cathode material is useful in the preparation of sodium ion batteries (claimed). ADVANTAGE - The method : is simple, and suitable for large-scale industrial production; improves the rate performance and cycle stability, and the electrochemical performance of sodium storage is better than that of pure NaxMnyCrz(PO4)n material. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a method for preparing double-carbon modified polyanionic sodium-ion battery cathode material, comprising (1) preparing a mixed solution of sodium acetate solution, manganese acetate tetrahydrate solution, chromium nitrate solution, ammonium dihydrogen phosphate and carbon-based material a, respectively, and stirring them in a water bath, preparing a dispersion of carbon-based material b, and ultrasonically dispersing, (2) adding the dispersion liquid of carbon-based material b, sodium acetate solution, manganese acetate tetrahydrate solution and chromium nitrate solution dropwise to the mixed solution of ammonium dihydrogen phosphate and carbon-based material a raw material, drying in a water bath after stirring to obtain a double-carbon modified polyanion type sodium-ion battery cathode material precursor, and (3) performing programmed sintering on the double-carbon modified polyanion type sodium ion battery cathode material precursor obtained in step (2) to obtain a double carbon modified polyanion type sodium ion battery cathode material.