• 专利标题:   Preparation of carbon fiber/graphite/epoxy resin prepreg used for preparing carbon fiber composite material involves preparing graphene/epoxy resin slurry, adding carbon fiber, soaking, friction rolling, drawing, winding, and drying.
  • 专利号:   CN105968718-A
  • 发明人:   ZHAO D, ZHANG W, LIN H, DONG H, WANG X
  • 专利权人:   UNIV BEIJING CHEM TECHNOLOGY
  • 国际专利分类:   C08J005/24, C08K003/04, C08K007/06, C08K009/02, C08K009/06, C08L021/00, C08L063/00
  • 专利详细信息:   CN105968718-A 28 Sep 2016 C08L-063/00 201709 Pages: 10 Chinese
  • 申请详细信息:   CN105968718-A CN10339876 20 May 2016
  • 优先权号:   CN10339876

▎ 摘  要

NOVELTY - Preparation of carbon fiber/graphite/epoxy resin prepreg comprises preparing graphene; mixing with N,N'-dicyclohexylcarbodiimide, dispersing in silane coupling agent solution, ultrasonically mixing for 1-3 for hours, stir-heating, centrifugally separating, washing with deionized water, and drying; adding epoxy resin, polyurethane modified liquid rubber and curing agent composition system, mechanically stirring, ultrasonically reacting, adding accelerant DMP-30, ultrasonically reacting, and vacuum drying; and adding carbon fiber, soaking, friction rolling, drawing, winding, and drying. USE - Method for preparing carbon fiber/graphite/epoxy resin prepreg used for preparing carbon fiber composite material (claimed). ADVANTAGE - The prepreg has optimal mechanical properties, bending strength of 1525.4 MPa, and interlaminar shear strength of 91.14 MPa at amount of 0.5 wt.%, increased bending strength and interlaminar shear strength at 15.41% and 14.14%, respectively, and simple process, and uses low toxicity solvents. DETAILED DESCRIPTION - Preparation of carbon fiber/graphite/epoxy resin prepreg comprises preparing graphene; mixing with N,N'-dicyclohexylcarbodiimide, dispersing in silane coupling agent solution, ultrasonically mixing for 1-3 for hours, stir-heating at 60-80 degrees C for 12-20 hours, centrifugally separating, washing with deionized water, and drying; adding epoxy resin, polyurethane modified liquid rubber and curing agent composition system, mechanically stirring, ultrasonically reacting for 4-8 hours, adding accelerant DMP-30, ultrasonically reacting for 1-2 hours, and vacuum drying; and adding carbon fiber, soaking, friction rolling, drawing, winding, and drying for 1-4 hours at 100-120 degrees C. An INDEPENDENT CLAIM is included for preparation of carbon fiber composite material comprising laminating prepreg by flat-bed pressing, curing, post-curing, and cooling to room temperature.