• 专利标题:   Preparing polyaniline nanowire-graphene oxide/graphene composite material useful as seawater batteries cathode material, comprises performing electrochemical deposition using prepared graphite paper with graphene oxide or graphene surface layer and stainless steel in acidic electrolyte with aniline.
  • 专利号:   CN114927638-A
  • 发明人:   ZHENG Y, MA A, WANG B, DENG S
  • 专利权人:   UNIV CENT SOUTH
  • 国际专利分类:   H01M004/08, H01M004/36, H01M004/583, H01M006/34
  • 专利详细信息:   CN114927638-A 19 Aug 2022 H01M-004/08 202302 Chinese
  • 申请详细信息:   CN114927638-A CN10739087 28 Jun 2022
  • 优先权号:   CN10739087

▎ 摘  要

NOVELTY - Preparing polyaniline nanowire-graphene oxide/graphene composite material comprises (i) taking graphite paper as an anode and stainless steel as cathode, performing electrochemical peeling in an oxidizing electrolyte to obtain graphite paper with surface layer containing graphene oxide or taking graphite paper as an anode and stainless steel as cathode and performing electrochemical peeling in the non-oxidizing electrolyte to obtain the graphene-containing graphite paper on the surface; and (ii) taking graphite paper containing graphene oxide or graphene on the surface layer as the anode and stainless steel as the cathode and performing electrochemical deposition in an acidic electrolyte containing aniline. The oxidizing electrolyte comprises at least one of nitric acid, sulfuric acid and/or perchloric acid. The non-oxidizing electrolyte comprises at least one of sulfuric acid, phosphoric acid, sodium hypophosphite, sodium dihydrogen phosphate and/or sodium sulfate. USE - The method is useful for preparing polyaniline nanowire-graphene oxide/graphene composite material is useful as cathode material for seawater batteries or zinc ion batteries (all claimed). ADVANTAGE - The method: generates polyaniline nanowires in situ by electrochemical deposition with high density and uniform diameter distribution; and prepares composite material as cathode material for seawater batteries or zinc ion batteries without separation to obtain seawater or zinc ion batteries with high energy density. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for polyaniline nanowire-graphene oxide/graphene composite material, prepared as mentioned above.