• 专利标题:   Preparation of graphene modified hard alloy by mixing graphene oxide suspension dispersion liquid with nano tungsten, cobalt and/or nickel, and chromium oxide powder, ball milling, granulating, and sintering.
  • 专利号:   CN102747243-A, CN102747243-B
  • 发明人:   CHEN M, WANG Y
  • 专利权人:   WANG Y
  • 国际专利分类:   C22C001/05, C22C029/08
  • 专利详细信息:   CN102747243-A 24 Oct 2012 C22C-001/05 201321 Pages: 9 Chinese
  • 申请详细信息:   CN102747243-A CN10262916 27 Jul 2012
  • 优先权号:   CN10262916

▎ 摘  要

NOVELTY - A graphene modified hard alloy is prepared by dispersing graphene oxide or graphene oxide and carbon powder in water and/or organic solvent to form dispersion liquid; mixing nano tungsten powder, cobalt powder and/or nickel powder and chromium oxide powder to form hard alloy raw material; ball milling at 100-250 rpm for 12-96 hours, drying, granulating by adding 1-10 wt.% forming agent, pressing at 200-400 MPa and forming; degreasing at 300-450 degrees C and 0.5-2 degrees C/minute for more than 3 minutes; and inert gas sintering, vacuum sintering, or low-pressure sintering at 1300-1500 degrees C. USE - Method for preparing a graphene modified hard alloy. ADVANTAGE - The method realizes the rapid preparation of hard alloy product, and improves the production efficiency and hard alloy comprehensive performance. It is suitable for industrial production.