• 专利标题:   Preparing coated cotton fabric, involves dispersing graphene oxide dispersion liquid into ethanol, performing ultrasonic treatment to obtain homogeneous phase dispersion liquid, dispersing ferrous chloride tetrahydrate and ferric chloride hexahydrate into ethanol to obtain mixed solution.
  • 专利号:   CN114703657-A
  • 发明人:   WANG L, RUAN S, WAN J
  • 专利权人:   UNIV ZHEJIANG SCITECH
  • 国际专利分类:   D06M101/06, D06M011/49, D06M011/74, D06M015/263
  • 专利详细信息:   CN114703657-A 05 Jul 2022 D06M-011/74 202277 Chinese
  • 申请详细信息:   CN114703657-A CN10414263 20 Apr 2022
  • 优先权号:   CN10414263

▎ 摘  要

NOVELTY - The preparation method of a coated cotton fabric involves: dispersing graphene oxide dispersion liquid into ethanol, and performing ultrasonic treatment to obtain homogeneous phase dispersion liquid; dispersing ferrous chloride tetrahydrate and ferric chloride hexahydrate into ethanol to obtain a mixed solution; mixing the homogeneous dispersion liquid with the mixed solution, adding aqueous ammonia, heating and stirring to obtain reduced graphene oxide-iron oxide black precipitate; dispersing the black precipitate into ethanol, carrying out ultrasonic treatment, and then transferring to a reaction kettle for vigorous stirring; adding 2-hydroxyethyl methacrylate, butyl acrylate and 2,2'-azo (isobutyronitrile) into the mixed solution, and carrying out heating copolymerization reaction to obtain a viscous polymer solution; placing the desized, washed and bleached all-cotton fabric into a mold, pouring the viscous polymer solution into the mold, and performing infiltration treatment. USE - Preparation method of a coated cotton fabric with efficient electromagnetic wave absorption performance. ADVANTAGE - The method uses polyacrylate as the polymer matrix of the coating material, and the polymer has good water resistance and elasticity. The wave-absorbing cotton fabric is prepared by the coating method, the method is simple to operate, and the prepared cotton fabric has excellent electromagnetic wave-absorbing performance. DETAILED DESCRIPTION - The preparation method of a coated cotton fabric with efficient electromagnetic wave absorption performance involves: weighing 16-22 mL graphene oxide dispersion liquid, dispersing the graphene oxide dispersion liquid into ethanol, and performing ultrasonic treatment for 20-40 minutes to obtain homogeneous phase dispersion liquid; dispersing ferrous chloride tetrahydrate and ferric chloride hexahydrate into ethanol to obtain a mixed solution; mixing the homogeneous dispersion liquid with the mixed solution, adding 37-43 mL aqueous ammonia, heating and stirring at 55-65 ℃ for 5-7 hours to obtain reduced graphene oxide-iron oxide black precipitate; dispersing the black precipitate into ethanol, carrying out ultrasonic treatment for 1.5-3 hours, and then transferring to a reaction kettle for vigorous stirring; adding 0.8-1.2 mL 2-hydroxyethyl methacrylate, 1.1-1.5 mL butyl acrylate and 4.2-5.4 mg 2,2'-azo (isobutyronitrile) into the mixed solution, and carrying out heating copolymerization reaction at 55-65 ℃ for 10-14 hours to obtain a viscous polymer solution; placing the desized, washed and bleached all-cotton fabric into a mold, pouring the viscous polymer solution into the mold, and performing infiltration treatment; and taking out the all-cotton fabric subjected to the soaking treatment for 9-13 hours, and drying at 60-80 ℃ for 15-18 hours.