• 专利标题:   Lead selenide quantum dot-graphene composite material used in thermoelectric application, comprises lead selenide quantum dots that are loaded on graphene surface.
  • 专利号:   CN105836716-A, CN105836716-B
  • 发明人:   DU F, LI J, JIANG C, ZHANG Y, WU Y, XIE S
  • 专利权人:   WUHAN INST TECHNOLOGY
  • 国际专利分类:   C01B019/04, C01B031/04, C01B032/184
  • 专利详细信息:   CN105836716-A 10 Aug 2016 C01B-019/04 201703 Pages: 11 Chinese
  • 申请详细信息:   CN105836716-A CN10176411 25 Mar 2016
  • 优先权号:   CN10176411

▎ 摘  要

NOVELTY - A lead selenide quantum dot-graphene composite material comprises lead selenide quantum dots that are loaded on the graphene surface. The quantum dots are uniformly distributed on both surfaces of graphene. The lead-selenide quantum dot has size of 2-30 nm. The number of layers of the graphene is 1-5. The length and width of the graphene are in the range of 500 nm-2.0 mu m. The mass ratio of graphene and lead selenide quantum dots is 0-1. USE - Lead selenide quantum dot-graphene composite material used in thermoelectric application. ADVANTAGE - The lead selenide quantum dot-graphene composite material is prepared by simple process conveniently with high electron transport property, and high Seebeck coefficient. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of lead selenide quantum dot loaded graphene composite material, which involves (a) adding soluble lead salt to aqueous graphene oxide solution to obtain a mixed solution, adding an alkaline solution to the mixed solution to a pH of 9-10 to obtain an oxidized graphene-lead ion complex solution, (ii) preparing selenium precursor solution under nitrogen atmosphere, (iii) adding selenium precursor solution to oxidized graphene-lead ion complex solution, where the ratio of selenium powder and lead nitrate is (1-10):1, reflux reacting at 20-180 degrees C for 1-24 hours under nitrogen protection atmosphere, and separating black solid, (iv) adding black solid to water, ultrasonically dispersing uniformly, adding reductant, adjusting the pH to 12-13 with alkali, reflux reacting at 40-100 degrees C for 2-24 hours, and isolating the resulting solid product.