• 专利标题:   Catalyst for manufacturing olefin polymer, comprises carbon material having preset molar ratio of oxygen atom with respect to carbon atom measured by X-ray photoelectron spectroscopy and specific surface area measured by BET multipoint method, organoaluminum compound, and transition metal compound.
  • 专利号:   JP2022071588-A
  • 发明人:   HARADA Y, TERAO H
  • 专利权人:   MITSUI CHEM INC
  • 国际专利分类:   C08F010/00, C08F004/64
  • 专利详细信息:   JP2022071588-A 16 May 2022 C08F-004/64 202251 Pages: 33 Japanese
  • 申请详细信息:   JP2022071588-A JP180632 28 Oct 2020
  • 优先权号:   JP180632

▎ 摘  要

NOVELTY - A catalyst comprises a carbon material (a) having a molar ratio of oxygen atom with respect to carbon atom of 0.018-0.400 measured by X-ray photoelectron spectroscopy and a specific surface area of 100-5000 m2/g measured by BET multipoint method, an organoaluminum compound (b), and a transition metal compound (c). USE - Catalyst is used for manufacturing olefin polymer (claimed) e.g. ethylene polymer. ADVANTAGE - The catalyst has high polymerization activity, and can be manufactured by economical method without using expensive organic aluminum oxy compound. The carbon material is efficiently dispersed in the catalyst. The carbon material has improved thermal conductivity, electroconductivity and weather resistance. DETAILED DESCRIPTION - A catalyst comprises a carbon material (a) having a molar ratio of oxygen atom with respect to carbon atom of 0.018-0.400 measured by X-ray photoelectron spectroscopy and a specific surface area of 100-5000 m2/g measured by BET multipoint method, an organoaluminum compound of formula: R'amAl(OR'b)nHpXq (b), and a transition metal compound of formula: Lm'MXn' (c). R'a,R'b = 1-15C hydrocarbyl; X = halo; m = 1-3; n,p,q = 0-2; m+n+p+q = 3; M = group 3 atom, group 4 atom, group 5 atom, group 6 atom, group 7 atom, group 8 atom, group 9 atom, group 10 atom, group 11 atom and lanthanide atom in periodic table; L = ligand comprising atom(s) chosen from boron, nitrogen, oxygen, phosphorus, sulfur and selenium; m' = 2 or more; n' = 1-4;and X = leaving group, preferably H, halo, hydrocarbyl, halo-containing group, silicon-containing group, oxygen-containing group, sulfur-containing group, nitrogen-containing group, phosphorus-containing group, boron-containing group, aluminum-containing group, conjugated diene-based derivative group or neutral ligand capable of coordinating with isolated electron pair. An INDEPENDENT CLAIM is included for manufacture of olefin polymer, which involves (i) polymerizing an olefin in the presence of the catalyst.