• 专利标题:   Preparing high energy density gallium(III) sulfide lithium/sodium ion battery cathode material by high-energy ball milling process, comprises e.g. stirring gallium and sulfur, ball milling stirred product and graphene oxide, and calcining.
  • 专利号:   CN112456543-A, CN112456543-B
  • 发明人:   ZHAO C, WEI Z
  • 专利权人:   UNIV SHENZHEN
  • 国际专利分类:   C01B017/02, C01B032/184, C01G015/00, H01M010/0525, H01M010/054, H01M004/58, H01M004/62
  • 专利详细信息:   CN112456543-A 09 Mar 2021 C01G-015/00 202128 Pages: 9 Chinese
  • 申请详细信息:   CN112456543-A CN11333809 24 Nov 2020
  • 优先权号:   CN11333809

▎ 摘  要

NOVELTY - Preparing high energy density gallium(III) sulfide lithium/sodium ion battery cathode material by high-energy ball milling process, comprises (i) stirring gallium and sulfur in a atom ratio of 2:3 at 25-35 degrees C for 18-48 hours to obtain stirred product, (ii) ball milling the stirred product of step (i) and graphene oxide at a mass ratio of 8:2 to obtain ball milled product, and (iii) calcining the ball milled product to obtain composite gallium(III) sulfide-sulfur-doped reduced graphene oxide i.e. high energy density gallium(III) sulfide lithium/sodium ion battery cathode material. USE - The gallium(III) sulfide lithium/sodium ion battery cathode material is useful in lithium/sodium-sulfur battery (claimed). ADVANTAGE - The cathode material: solves the problem of dissolving polysulfide; solves the problem of energy loss caused by pulverization of materials with high energy density; and retains 80% reversible cycle energy after 1500 cycles in the button battery test.