• 专利标题:   Preparing metal organic framework-carbon composite material used to remove phosphate in sewage comprises stirring e.g. single-walled carbon nanotubes/reduced graphene oxide in methanol, filtering mixed solution, and vacuum drying.
  • 专利号:   CN112642402-A
  • 发明人:   WANG Y, LI B, YANG J, QI Z, SHANG Y, PENG Y
  • 专利权人:   UNIV BEIJING TECHNOLOGY
  • 国际专利分类:   B01J020/22, B01J020/30, C02F001/28, C02F101/10
  • 专利详细信息:   CN112642402-A 13 Apr 2021 B01J-020/22 202142 Pages: 8 Chinese
  • 申请详细信息:   CN112642402-A CN10029242 11 Jan 2021
  • 优先权号:   CN10029242

▎ 摘  要

NOVELTY - Preparing metal organic framework-carbon composite material comprises (a) adding single-walled carbon nanotubes/reduced graphene oxide and methyl imidazole in methanol, and then stirring the mixture ultrasonically for 30-40 minutes to prepare uniform solution, (b) dispersing zinc nitrate hexahydrate in methanol, stirring for 10-15 minutes, and mixing to obtain zinc nitrate solution, where the molar ratio of zinc to hydroxide provided by single-walled carbon nanotubes/reduced graphene oxide is 1:1-1:6, and the mass concentration ratio of zinc and methyl imidazole is 1:2-1:6, (c) adding the above solution to the mixed solution prepared in the step (a), then adding the mixture into stainless steel autoclave lined with polytetrafluoroethylene, and maintaining at 90 degrees C for 6-7 hours, and (d) filtering the mixed solution, and vacuum drying at 90 degrees C for 2-3 hours. USE - The composite material is useful for removing phosphate in sewage.