• 专利标题:   Composite used for forming anode of electrochemical device, comprises graphene, and nanoparticles of anode active material of electrochemical device, which are conformally coated and networked by graphene.
  • 专利号:   WO2022039944-A1, WO2022039944-A9
  • 发明人:   HERSAM M C, LIM J
  • 专利权人:   UNIV NORTHWESTERN
  • 国际专利分类:   C01B032/194, H01M010/052, H01M010/0525, H01M004/02, H01M004/36, H01M004/48, H01M004/485, H01M004/62
  • 专利详细信息:   WO2022039944-A1 24 Feb 2022 202221 Pages: 66 English
  • 申请详细信息:   WO2022039944-A1 WOUS044873 06 Aug 2021
  • 优先权号:   US067948P

▎ 摘  要

NOVELTY - A composite comprises graphene, and nanoparticles of an anode active material of an electrochemical device. The nanoparticles are conformally coated and networked by graphene. USE - Composite is used for forming anode (claimed) of electrochemical device e.g. rechargeable lithium-ion battery used for portable electronic device, electric vehicle and grid-level energy storage system. ADVANTAGE - The anode formed using the composite has suppressed surface phase transformation and reduced solid-electrolyte interphase formation during electrochemical cycle, and provides battery having high volumetric energy density and power density, due to the presence of the conductive graphene coating which mitigates solid-electrolyte interphase formation, reduces interfacial resistance, and minimizes over-potentials without compromising lithium-ion diffusion, high rate performance, improved safety and stability, prolonged cycle life, minimal structural changes, and suppressed surface side reactions in lithium-ion batteries. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) anode, which comprises the composite; and (2) formation of the composite, which involves (i) agitating a mixture of nanoparticles, graphene and ethyl cellulose in a solvent to disperse nanoparticles and graphene with the ethyl cellulose so as to prevent aggregation of nanoparticles, and (ii) annealing the agitated mixture at a temperature for a period of time to decompose the ethyl cellulose.