▎ 摘 要
NOVELTY - Composite particulate comprises one or more than one anode active material particles that are dispersed in a high-elasticity polymer matrix or encapsulated by a high-elasticity polymer shell. The composite particulate has a diameter from 10 nm to 50 µm. The high-elasticity polymer matrix or shell has a recoverable elastic tensile strain no less than 5%, when measured without an additive or reinforcement dispersed, and a lithium ion conductivity no less than 10-8S/cm at room temperature. The high-elasticity polymer comprises a polymer derived from a monomer selected from vinyl sulfite, ethylene carbonate, methyl methacrylate, vinyl acetate, fluorinated monomers having unsaturation for polymerization, sulfones, sulfides, nitriles, sulfates, siloxanes, and silanes. USE - Composite particulate for use in anode for lithium battery, such as lithium-ion battery, lithium metal battery, lithium-sulfur battery, lithium-selenium battery, or lithium-air battery (all claimed). ADVANTAGE - The composite particulates when used as an anode active material in lithium battery, enables a lithium battery to exhibit a high cycle life, high reversible capacity, low irreversible capacity, small particle sizes (for high-rate capacity), and compatibility with commonly used electrolytes. The production method can readily and easily produce such composite particulates in large quantities. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: a. an anode, which comprises multiple composite particulates as an anode material; b. a method for producing the anode, which involves: i. dispersing multiple particles of an anode active material and a conductive additive in a precursor polymer solution to form a suspension where the precursor solution comprises at least a curing agent dissolved or dispersed in a reactive liquid medium that comprises a monomer or oligomer; ii. dispensing and depositing a layer of the suspension onto a solid substrate surface; and iii. curing the monomer or oligomer to form the anode; c. a lithium battery, which comprises anode, a cathode, and an electrolyte in ionic contact with the anode and the cathode; and d. a method for manufacturing multiple composite particulates, which involves: i. dispersing multiple particles of an anode active material in a precursor polymer solution to form a suspension where these particles are fully embedded or immersed in the precursor solution; ii. operating a secondary particle-forming procedure to shape the suspension into multiple droplets and remove the liquid solvent from the droplets; and iii. curing the monomer or oligomer to form the composite particulates where particulate comprises one or multiple anode active material particles that are dispersed and embedded in a polymer matrix or encapsulated by a polymer shell. DESCRIPTION OF DRAWING(S) - The drawing shows schematic view of three types of composite particulates. 32,42High elasticity polymer matrix 34Anode active material primary particles 36Three dimensional network of electron conducting pathways 48Shell 50Pores 52Conductive protection shell or coating