• 专利标题:   Preparation of manganese dioxide comprises adding graphene oxide to deionized water, sonicating, mixing with manganese dioxide precursor and citric acid, stir-heating, cooling, aging, drying, calcining, and treating with sulfuric acid.
  • 专利号:   CN105185977-A, CN105185977-B
  • 发明人:   GUO S, LIU Y, SONG J, ZHENG P, YUAN X, ZHANG J, ZHANG L
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   C01G045/02, H01M004/1391, H01M004/50
  • 专利详细信息:   CN105185977-A 23 Dec 2015 H01M-004/50 201630 Pages: 7 English
  • 申请详细信息:   CN105185977-A CN10658466 13 Oct 2015
  • 优先权号:   CN10658466

▎ 摘  要

NOVELTY - Preparation of manganese dioxide comprises taking graphene oxide, adding to deionized water, and sonicating to prepare graphene oxide dispersion; adding manganese dioxide precursor and citric acid, mixing, and adjusting pH to 1-7 with aqueous ammonia; stir-heating to 50-90 degrees C for 3-12 hours, cooling to 18-25 degrees C, aging for 24 hours, and drying at 70-130 degrees C for 4-12 hours; and calcining at 300-700 degrees C for 3-7 hours, and treating with 2 mol/L concentrated sulfuric acid for 1-4 hours. USE - Method for preparing manganese dioxide used for lithium ion battery cathode material (claimed). ADVANTAGE - The method is simple and has low energy consumption. The prepared manganese dioxide is E-type manganese dioxide with distinctive structural features and nanoparticle shape having average size of 20 nm and has high specific surface area and excellent electrochemical performance. The cathode material has high electrochemical performance.