• 专利标题:   Composite material used as magnetic separation catalyst in wastewater treatment, electromagnetic shielding, and wave absorption, comprises carbon-containing ferromagnetic nanometer metal particles coated on graphene material.
  • 专利号:   CN101710512-A, CN101710512-B
  • 发明人:   FAN Z, WEI T
  • 专利权人:   UNIV HARBIN ENGINEERING
  • 国际专利分类:   B22F001/02, C01B031/00, C01B031/02, H01F001/00, H01F001/047
  • 专利详细信息:   CN101710512-A 19 May 2010 H01F-001/00 201038 Pages: 7 Chinese
  • 申请详细信息:   CN101710512-A CN10073233 20 Nov 2009
  • 优先权号:   CN10073233

▎ 摘  要

NOVELTY - A composite material comprises a graphene material, and carbon-containing ferromagnetic nanometer metal particles uniformly coated on the surface of the graphene material. The graphene material comprises a single graphite layer that is less than 50 nm thick. The metal particle has a diameter of 2-100 nm. The ferromagnetic metal is iron, cobalt, and/or nickel. The mass ratio of the metal to the carbon is 1-20:1. USE - A composite material used as a magnetic separation catalyst in wastewater treatment, electromagnetic shielding, and wave absorption. ADVANTAGE - The composite material has excellent magnetic performance and good conductivity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparing the composite material, comprising: (A) ultrasonically dispersing 0.1-10 mg/mL graphite oxide solution for 0.5-5 hours to obtain a graphene oxide dispersing agent; (B) adding 0.1-5 mol/L ferromagnetic metal salt solution, where the mass ratio of the soluble salt of the ferromagnetic metal to the graphite oxide is 0.1-100:1; (C) mixing for 0.5-10 hours; (D) preparing 0.1-5 mol/L solution by using a precipitant with the molar ratio to the soluble salt of the transitional metal of 1-20:1; (E) adding the solution into the graphite oxide dispersing agent at 10 mL/minute; (F) drastically mixing, and reacting at 0-100 degrees C for 0.5-10 hours; (G) filtering, completely washing, and drying the material to obtain a composite powdery body; (H) heating the powdery body to 500-800 degrees C at 5-50 degrees C/minute at nitrogen or argon atmosphere; (I) inflating the mixed gas at 10-100 mL/minute for chemical vapor deposition for 1-60 minutes; and (J) cooling the reactants at nitrogen or argon atmosphere to room temperature.