• 专利标题:   Preparing laminated fluorinated graphene for positive electrode of lithium battery by subjecting layer graphene and stabilizer to shear emulsification, homogenizing, freeze-drying, annealing and performing high-temperature fluorination.
  • 专利号:   CN112661146-A, CN112661146-B
  • 发明人:   PAN Y, WANG X, PAN J, LUO Z, CHANG Q
  • 专利权人:   UNIV XIANGTAN
  • 国际专利分类:   C01B032/10, C01B032/194, H01M004/587, H01M006/16
  • 专利详细信息:   CN112661146-A 16 Apr 2021 C01B-032/194 202149 Pages: 15 Chinese
  • 申请详细信息:   CN112661146-A CN11555033 23 Dec 2020
  • 优先权号:   CN11555033

▎ 摘  要

NOVELTY - Method for preparing laminated fluorinated graphene for positive electrode of lithium battery involves subjecting mixture of N-layer graphene and stabilizer to shear emulsification, homogenizing, freeze-drying and annealing to obtain laminated graphene, and performing high-temperature fluorination of the laminated graphene assisted by alloy balls to obtain the product, where the stabilizer is polyvinyl alcohol, the mass ratio of graphene and polyvinyl alcohol is (1-2):1, and the ratio of double covalent bond on the surface of the laminated fluorinated graphene is 10-20%. USE - The method is useful for preparing laminated fluorinated graphene for positive electrode of lithium battery. ADVANTAGE - The method uses fluorinated graphene which has a laminated sheet-layer stacking structure to provide more reaction sites, and retains 10-20% of C=C bonds on its surface to improve the electrical conductivity of the material. DETAILED DESCRIPTION - Method for preparing laminated fluorinated graphene for positive electrode of lithium battery involves subjecting mixture of N-layer graphene and stabilizer to shear emulsification, homogenization, freeze-drying and annealing to obtain laminated graphene, and performing high-temperature fluorination of the laminated graphene assisted by alloy balls to obtain the product, where the stabilizer is polyvinyl alcohol, the mass ratio of graphene and polyvinyl alcohol is (1-2):1, and the ratio of double covalent bond (C=C bond) on the surface of the laminated fluorinated graphene is 10-20%. N = 3-10.