• 专利标题:   Tungsten-copper-graphene oxide-based material for making electric arc contacts e.g. contact points, comprises tungsten, copper and graphene oxide, and provided in form of cylindrical semi-finished products having preset diameter and height.
  • 专利号:   RO135323-A2
  • 发明人:   LUNGU M V, ION I, TALPEANU D, PATROI D, MARIN M, MARINESCU V E, SBARCEA B G, LUCACI M, GODEANU P, BARBU A C
  • 专利权人:   INST NAT CERCDEZVOLTARE PENTRU ING ELEC
  • 国际专利分类:   B22F003/12, C22C001/04, C22C038/12, C22C038/20
  • 专利详细信息:   RO135323-A2 29 Nov 2021 C22C-038/12 202200 Pages: 1 English
  • 申请详细信息:   RO135323-A2 RO000276 21 May 2020
  • 优先权号:   RO000276

▎ 摘  要

NOVELTY - A tungsten-copper-graphene oxide-based electrical contact material comprises 75-80 %mass tungsten, 20-25 %mass copper and 0.5 %mass graphene oxide (GO). The electrical contact material is provided in the form of cylindrical semi-finished products having a diameter of 20-60 mm and a height of 3-10 mm. USE - Tungsten-copper-graphene oxide-based material used for making electric arc contacts e.g. protection rings and contact points for equipping medium-voltage switching device and high-voltage switching device. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the electrical contact material, which involves adding tungsten powder, copper powder and GO powder in a stoichiometric ratio, introducing 500-1000 g tungsten-copper-GO composite powder into 450-900 ml ethyl alcohol solution, homogenizing at room temperature with a mechanical stirrer at a speed of 300-350 rpm for 2-3 hours, drying for 6-8 hours in a vacuum oven at 80-90° C, introducing the dried tungsten-copper-GO composite powder in a non-granulated state into a high density graphite mold having ladle inner diameter of 20.8-60.8 mm, uniaxially pressing using 0.4 mm thick graphite foils, and sintering in a vacuum spark plasma sintering equipment to obtain sintered cylindrical semi-finished products having density of 13.59-14.41 g/cm3and indented hardness of 3.23-4.08 GPa. The tungsten powder contains polyhedral microcrystalline particles having an average Fisher diameter of 4.2 μ m and an apparent density of 3.55 g/cm3. The copper powder has a granulation of less than 63 μ m and a bulk density of 1.6 g/cm3. The GO powder contains multilayer GO having a lateral dimension of 5-15 nm and a height of 10-15 nm, and has apparent density of 0.24 g/cm3. The multilayer GO contains 73-75 %mass carbon, 23-24 %mass oxygen and 1.3-1.7 %mass nitrogen.