• 专利标题:   Preparing graphene/metal-organic framework porous composites hydrogel and aerogel comprises e.g. adding graphene or oxidized graphene dispersion into container and compounding metal-organic frameworks crystal and graphene or graphene oxide.
  • 专利号:   CN107215863-A
  • 发明人:   CAO X, XU X, XU L
  • 专利权人:   UNIV ZHEJIANG TECHNOLOGY
  • 国际专利分类:   C01B032/184, C01B032/194
  • 专利详细信息:   CN107215863-A 29 Sep 2017 C01B-032/194 201772 Pages: 25 Chinese
  • 申请详细信息:   CN107215863-A CN10243644 14 Apr 2017
  • 优先权号:   CN10243644

▎ 摘  要

NOVELTY - Preparing graphene/metal-organic framework porous composites hydrogel and aerogel comprises e.g. taking clean container, adding graphene or oxidized graphene dispersion, adding MOFs crystal powder, sealing container, compounding metal-organic frameworks crystal and graphene or graphene oxide obtaining graphene/metal-organic framework porous composite hydrogel, then freeze-drying to obtain graphene/metal-organic framework porous composite airgel, where mass ratio between metal-organic frameworks crystal powder and graphene or graphene oxide is 1:100-100:1. USE - The method is useful for preparing graphene/metal-organic framework porous composites hydrogel and aerogel (claimed). ADVANTAGE - The method has mild reaction conditions, simple preparation, and prevents agglomeration of graphene or graphene oxide and MOFs. DETAILED DESCRIPTION - Preparing graphene/metal-organic framework (MOF) porous composites hydrogel and aerogel comprises taking clean container, adding graphene or oxidized graphene dispersion, then adding MOFs crystal powder, sealing container, oscillating or stirring, promoting graphene or graphene self-assembled three-dimensional frame structure, and compounding metal-organic frameworks crystal and graphene or graphene oxide obtaining graphene/metal-organic framework porous composite hydrogel, then freeze-drying to obtain graphene/metal-organic framework porous composite airgel, where mass ratio between metal-organic frameworks crystal powder and graphene or graphene oxide is 1:100-100:1, graphene/metal-organic framework porous composite airgel having self-supporting porous structure and retains integrity of graphene or oxidized graphene.