• 专利标题:   New raphene nano-segment molecule containing azulene unit-azulene and rubicene compound i.e. azuleno(5,6,7,8,1-uvwxa)cyclohepta(ijkl)rubicene compound useful in near-infrared absorption photodetection, and field-effect transistors, organic solar cells, organic light-emitting diodes.
  • 专利号:   CN115215720-A
  • 发明人:   LI C, ZHANG G, ZHANG X, QIN L, ZHANG D
  • 专利权人:   CHINESE ACAD SCI CHEM INST
  • 国际专利分类:   B82Y030/00, B82Y040/00, C07C013/62, C07C002/86, C07C041/14, C07C043/21, H01L051/00, H01L051/05, H01L051/30, H01L051/42, H01L051/46, H01L051/50, H01L051/54
  • 专利详细信息:   CN115215720-A 21 Oct 2022 C07C-013/62 202312 Chinese
  • 申请详细信息:   CN115215720-A CN10419849 19 Apr 2021
  • 优先权号:   CN10419849

▎ 摘  要

NOVELTY - Graphene nano-segment molecule containing azulene unit-azulene and rubicene compound (T) i.e. azuleno5,6,7,8,1-uvwxacycloheptaijklrubicene compounds (I), or (II), is new. USE - (T) is useful in near-infrared absorption photodetection, field-effect transistors, organic solar cells, and organic light-emitting diodes (claimed). ADVANTAGE - (T): have unique photophysical and electrochemical properties, and have good photoelectric functions. DETAILED DESCRIPTION - Graphene nano-segment molecule containing azulene unit-azulene and rubicene compound (T) i.e. azuleno5,6,7,8,1-uvwxacycloheptaijklrubicene compounds of formulae (I), or (II), is new. R1and R2= H, fluoro, chloro, bromo, iodo, trifluoromethyl, nitro, ester group, carboxy, 4-18C straight-chain or branched-chain alkyl, 4-18C linear or branched alkoxy, aromatic ring (optionally substituted with H, fluoro, chloro, bromo, iodo, trifluoromethyl, nitro, ester group, carboxy, 4-18C straight chain alkyl or branched chain alkyl, 4-18C linear or branched alkoxy, 4-18C straight chain or branched chain alkylamino, trimethylsilyl, triisopropylsilyl, tert-butyldimethylsilyl, or 1,1-dimethylhydroxymethyl), 4-18 C straight chain or branched chain alkylamino, trimethylsilyl, triisopropylsilyl, tert-butyldimethylsilyl or 1,1-dimethylhydroxymethyl; and aromatic ring = benzene ring, thiophene ring, pyridine ring, pyrrole ring, furan ring, pyrrole ring, naphthalene ring, anthracycline, pyrene ring or perylene ring. An INDEPENDENT CLAIM is included for preparation of (T).